Modified clays were used to remove ethyl acetate from aqueous solutions. These clays were regenerated using supercritical CO2. Structural changes in the montmorillonite clay after treatment with quaternary amines were studied. The surface properties of the modified clay changed from highly hydrophilic to highly organophilic. The clay was regenerated by percolation of a stream of CO2 through the...

Project Goals: We are developing Bacillus megaterium as a host for continuous biofuel production coupled with in situ product extraction by supercritical CO2 (scCO2) stripping. We employ a cross-disciplinary collaborative approach to achieve the following: (1) Develop a supercritical CO2 tolerant strain of B. megaterium into a bioproduction host for biofuels (2) Engineer de novo pathways for bi...

When supercritical CO2 is dissolved in an ionic liquid, its partial molar volume is much smaller than that observed in most other solvents. In this article we explore in atomistic detail and explain in an intuitive way the peculiar volumetric behavior experimentally observed when supercritical CO2 is dissolved in 1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim+] [PF6(-)]). We also provid...

Fabrication of nano-structured materials has been developed by performing pulsed laser ablation of copper, gold, and silver plates in supercritical CO2. The metal nano-structured particles were successfully generated with allowing the selective generation of clusters. Laser ablation was performed with an excitation wavelength of 532 nm. On the basis of the experimental result, both surface of a...

Nuclear energy can be used as the primary energy source in centralized hydrogen production through high-temperature thermochemical processes, water electrolysis, or high-temperature steam electrolysis. Energy efficiency is important in providing hydrogen economically and in a climate friendly manner. High operating temperatures are needed for more efficient thermochemical and electrochemical hy...

In this study the first supercritical fluid based protocol for the extraction, analysis, and isolation of six polar compounds, i.e., o-vanillin (1), styracin (2), vanillin (3), trans-cinnamic acid (4), vanillic acid (5), and shikimic acid (6), was developed. First, eight styrax resin products (R1-R8) obtained from various Liquidambar tree species, which are known to contain compounds 2-6, were ...

Supercritical fluid extraction (SCFE), based on the utilization of a fluid under supercritical conditions, is a technology suitable for extraction and purification of a variety of compounds, particularly those that have low volatility and/or are susceptible to thermal degradation. The interest in SCFE is promoted by legal limitations of conventional solvents for food and pharmaceutical uses. Th...

Gold nanoclusters and doxorubicin dual-loaded liposomes were prepared by using a supercritical CO2 method, and developed toward intracellular fluorescent thermometry, photothermal-triggered drug release and tumor therapy.

In the present study, Radix Codonopsis was extracted by supercritical CO2 extraction. As Ointment collecting rate and the yield of stigmasterol are index, Various reaction parameters were changed to attain the optimal conditions. The appropriate process conditions are size 40 60Mesh, 30 Mpa pressure, temperature 65 °C, 120 min, entrainer Alcohol dynamic extraction (entrainer pump flow rate of 1...

Milk fat was fractionated into liquid (m.p. congruent to 12 degrees C), intermediate (m.p. congruent to 21 degrees C) and solid (m.p. congruent to 39 degrees C) fractions by three different processes--melt crystallization, short-path distillation and supercritical CO2 extraction--and the cholesterol content of these fractions determined. Cholesterol was enriched in the liquid fractions from all...