نتایج جستجو برای: sulfoxide

تعداد نتایج: 9050  

Journal: :The Journal of organic chemistry 2001
J W Cubbage Y Guo R D McCulla W S Jenks

Gas-phase activation data were obtained for model sulfoxide elimination reactions. The activation enthalpy for methyl 3-phenylpropyl sulfoxide is 32.9 +/- 0.9 kcal/mol. Elimination by methyl vinyl sulfoxide to form acetylene has an enthalpic barrier of 41.6 +/- 0.8 kcal/mol and that of 3-phenylpropyl methanesulfinate to form hydrocinnamaldehyde is 34.6 +/- 0.6 kcal/mol. Calculations at the MP2/...

Journal: :Free radical biology & medicine 2012
Nancy B Wehr Rodney L Levine

Methionine residues in protein can be oxidized by reactive oxygen or nitrogen species to generate methionine sulfoxide. This covalent modification has been implicated in processes ranging from normal cell signaling to neurodegenerative diseases. A general method for detecting methionine sulfoxide in proteins would be of great value in studying these processes, but development of a chemical or i...

Journal: :Proceedings of the National Academy of Sciences of the United States of America 1978
A F Miranda E G Nette S Khan K Brockbank M Schonberg

Application of dimethyl sulfoxide to proliferating L8 myoblasts (an established cell line of rat skeletal muscle) for 72 hr completely prevented fusion and induction of creatine phosphokinase (EC 2.7.3.2) activity (an indicator of muscle differentiation). The growth pattern changed from the usual sheets of randomly oriented cells to flattened, whorled monolayers of elongated fibroblast-like cel...

Journal: :The Journal of biological chemistry 1984
J C Halle C Pichon F Terrier

A 1H NMR study of urocanic acid dissolved in water/dimethyl sulfoxide mixtures together with potentiometric determinations of its two successive acidities in the same solutions reveal that a proton is transferred from the imidazolium ring to the carboxylate group when the amount of dimethyl sulfoxide is increased. An analysis of the potentiometric data by means of the classical Hammett linear r...

Journal: :The Journal of Cell Biology 1983
L H English I G Macara L C Cantley

Friend murine erythroleukemia cells underwent apparently normal erythropoiesis when treated with dimethyl sulfoxide. One of the earliest events associated with this induction was a decrease in ouabain sensitive 86Rb+ uptake, an assay of the plasma membrane Na,K(ATPase). Ammonium vanadate (10 microM) blocked differentiation of these cells without affecting cell viability. Vanadium was taken up b...

Journal: :Cancer research 1973
J Warren M R Sacksteder B M Ellis R D Schwartz

The i.m. injection of dimethyl sulfoxide prior to the infection of quail with Rous sarcoma virus strain 0 and of mice with Moloney sarcoma virus resulted in increased virus titers, decreased incubation time to tumors and, in the case of Moloney sarcoma virus, decreased spontaneous regressions. Dimethyl sulfoxide administered at the time of or after infection was without effect. This compound al...

Journal: :Journal of Synthetic Organic Chemistry, Japan 1989

Journal: :Acta Crystallographica Section E Structure Reports Online 2009

Journal: :Journal of nematology 1993
R F Davis A W Johnson R D Wauchope

The degradation of fenamiphos, fenamiphos sulfoxide, and fenamiphos sulfone was determined in a greenhouse experiment using autoclaved and nonautoclaved soil from field plots treated or not treated with fenamiphos. Fenamiphos degradation and formation of fenamiphos sulfoxide was faster in uonautoclaved soil than in autoclaved soil. In nonautoclaved soil, previous exposure to fenamiphos was asso...

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