Non-vinyl-based ‘grafted from’ polymer brushes have generated much interest and growth in the past decade due to potential for stiffer backbones, long-range order, new backbone functional groups, compared traditional vinyl-based brushes. This area of has been spurred on by recent advancements polymerization techniques, such as chain-growth condensation polymerization, that allow conversion step...

Radical-mediated thiol-yne step-growth photopolymerizations are utilized to form highly cross-linked polymer networks. This reaction mechanism is shown to be analogous to the thiol-ene photopolymerization; however, each alkyne functional group is capable of consecutive reaction with two thiol functional groups. The thiol-yne reaction involves the sequential propagation of a thiyl radical with e...

Linear assemblies of nanoparticles show promising applications due to their collective electronic, optical and magnetic properties. Rational design and controllable organization of nanoparticles in one-dimensional structures can strongly benefit from the marked similarity between conventional step-growth polymerization reactions and directional step-wise assembly of nanoparticles in linear chai...

In free-radical polymerization, a monomer-initiator mixture is converted into a polymer. Depending on initial and boundary conditions, free-radical polymerization can occur either in a bulk mode (BP) or in a frontal mode (FP) via a propagating selfsustaining reaction front. The main goal of this paper is to study the role that bulk polymerization plays in frontal polymerization processes for va...

The inherent skeletal and thermal features to forge polymers by step-growth polymerization are conflicting with any depolymerization strategies via cascade back-biting reactions that necessitate adequate ceiling temperature, spacers, functionalities create cyclic compounds. Here, we report the edition of poly(carbonate-urea)s poly(carbonate-amide)s depolymerized on demand into their native prec...

ETWEEN 1947 AND 1962, the population of the United States grew at an average annual rate near 2 percent, a large increase from the average annual growth rate near 1 percent during the 20 years prior to World War II. Moreover, since 1962, the average population growth rate has fallen to its pre-war level. This large but temporary increase in the population growth rate, more familiarly called the...