Mots-clé PVD-CVD, Sol-gel processing, Monte Carlo simulation, thin film islanding. PACS 04A25 The synthesis of self-organized quantum dots (QD’s) can be achieved through bottom up layer by layer deposition processes as chemical vapor deposition (CVD) or physical vapor deposition (PVD). However, QD’s may also be synthesized via sol-gel route, which involves a spontaneous evolution from thin film...

................................................................................... viii CHAPTER 1. INTRODUCYION ........................................................... 1 1.1 Motivation ................................................................................. 1 1.2 Outline ..................................................................................... 2 CHAPTER 2. SOL-GEL PHOT...

the synthesis of titania via sol-gel method has been widely studied. in the present work, titania was deposited onto a titanium substrate via sol-gel method. different processing parameters such as the repetition number of dipping/heat treatment process and dipping time have been studied to obtain the homogenous titania coating. phase and microstructural evaluation of the powder and coating sam...

to improve the corrosion protection of copper metal, 0.01m concentration of 1h-1,2,4-triazole-3-thiol (tat) was incorporated into the hybrid sol-gel monolayers containing 3-glycidoxypropyltrimethoxysilane (gptms) and tetraethoxysilane (teos). it was further subjected to hydrolysis and condensation reaction to form a sol-gel matrix. the tat-doped hybrid sol-gel coating was applied over the coppe...

Light transducing phycobiliproteins are encapsulated in optically transparent sol-gel matrices. Absorption and fluorescence spectroscopies are used to characterize the effect of the sol-gel encapsulation on the conformation and aggregation states of the three major phycobiliproteins present in phycobilisomes: phycoerythrin, phycocyanin, and allophycocyanin. It is found that the effects of sol-g...

Sol-gel derived silica possess many promising features, including low-temperature preparation procedure, porosity, chemical and physical stability. Applications exploiting porous materials to encapsulate sensor molecules, enzymes and many other compounds, are developing rapidly. In this paper some potential applications, with emphasis on biomedical and environmental ones, are reviewed. The mate...