Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.

Introduction: Ca-Al-rich inclusions (CAIs) from Allende usually have secondary alteration phases such as anorthite, grossular, sodalite, and nepheline [1-3]. Although these phases are considered to have been formed by relatively low temperature reactions between CAIs and a surrounding nebular gas [1, 2], it is not well known that when such processes occurred. 36 Cl-36 S and

A  facile  effective  stirring  aging  at  room  temperature  prior  to  conventional  hydrothermal treatment was employed in the template-free synthesis of micro- and nano-crystalline sodalites with  two  different  initial  gel  compositions.  The  effect  of  initial  Si/Al  molar  ratio,  NaOH concentration and stirring aging time were investigated on the morphology and particle size of the...

a  facile  effective  stirring  aging  at  room  temperature  prior  to  conventional  hydrothermal treatment was employed in the template-free synthesis of micro- and nano-crystalline sodalites with  two  different  initial  gel  compositions.  the  effect  of  initial  si/al  molar  ratio,  naoh concentration and stirring aging time were investigated on the morphology and particle size of the...

Isomorphic substitutions of extra-framework components in sodalite-group aluminosilicate minerals and their thermal conversions have been investigated using infrared, Raman, electron spin resonance (ESR), as well ultraviolet, visible near infrared (UV–Vis–near IR) absorption spectroscopy methods involving chemical X-ray diffraction data. Sodalite-related from gem lazurite deposits (haüyne, lazu...

In this scientific research, for the first time, the removal of radioactive strontium-90 (90Sr) by γ-MnO2-AgA zeolite as a novel nanocomposite adsorbent was accomplished under different conditions such as pH, temperature, adsorbent amount and the contact time that are examined from drinking water of Ramsar city and monitored via Ultra Low-Level Liquid Scintillation Counting (LSC) technique. Pri...

microporous hydroxy-sodalite zeolite membranes with different morphologies were synthesized via secondary growth technique with vacuum seeding on tubular α-al2o3 supports at two different synthesis conditions (i.e. two different routes). microstructures of the synthesized membranes were characterized by x-ray diffraction (xrd), scanning electron microscope (sem) and single gas permeation using ...

Two processes for extracting alumina from low-grade ores are described, one applicable to both clays and high-silica bauxites, and the other only to bauxites. In the former process, a line-containing sinter is prepared and annealed by cooling it slowly through the range of 1,3000 to 1,2000 C. The annealed sinter dusts to a powder which requires no grinding. This material is extracted with a sol...