The studies include the results and discussion related with reaction of Fe2O3 with Na2SO4 in presence of SO2 (g) at 800 and 900 C. The iron oxides are produced by the oxidation of iron base alloys in many industrial operations. The metal oxide undergoes certain high temperature chemical reactions in presence of a gas (such as SO2) and molten salts (say Na2SO4). The thermo-gravimetric studies h...

The increase in the oxidation state of the atmosphere during Earth history is well documented, but not the reasons for this process. The course of atmospheric evolution has been dominated by the effects of photosynthesis and by the composition of volcanic gases. The H2/H2O ratio of volcanic gases has remained essentially constant during most of Earth history. It is here proposed that their CO2/...

There is significant interest in development of efficient catalyst-sorbents for the capture and conversion of sulfur-compounds such as H2S and SO2. In this work, ultra-high vacuum (UHV) techniques have been used to carefully prepare and thoroughly characterize amorphous carbon (a-C) thin films as models of activated carbon sorbents. Films with modified surface chemistries were prepared by oxida...

The oxidation of SO2 to sulfate is a key reaction in determining the role of sulfate in the environment through its effect on aerosol size distribution and composition. Sulfur isotope analysis has been used to investigate sources and chemical processes of sulfur dioxide and sulfate in the atmosphere, however interpretation of measured sulfur isotope ratios is challenging due to a lack of reliab...

Torres Filho IP, Terner J, Pittman RN, Proffitt E, Ward KR. Measurement of hemoglobin oxygen saturation using Raman microspectroscopy and 532-nm excitation. J Appl Physiol 104: 1809–1817, 2008. First published March 27, 2008; doi:10.1152/japplphysiol.00025.2008.— The resonant Raman enhancement of hemoglobin (Hb) in the Q band region allows simultaneous identification of oxyand deoxy-Hb. The hem...

The oxidation of sulfur dioxide to sulfur trioxide over supported vanadium oxide catalysts occurs as both a primary and secondary reaction in many industrial processes, e.g., the manufacture of sulfuric acid, the selective catalytic reduction of NOx with ammonia and the regeneration of petroleum re®nery cracking catalysts. This paper discusses the fundamental information currently available con...

Sulphuric acid is an important factor in aerosol nucleation and growth. It has been shown that ions enhance the formation of sulphuric acid aerosols, but the exact mechanism has remained undetermined. Furthermore some studies have found a deficiency in the sulphuric acid budget, suggesting a missing source. In this study the production of sulphuric acid from SO2 through a number of different pa...

Single-photon ionization through vacuum ultraviolet (VUV, 10.5 eV) and soft X-ray (extreme ultraviolet, EUV, 26.5 eV) laser radiation is successfully employed for the study of the reactions of neutral vanadium oxide clusters (V(m)O(n)) with sulfur dioxide (SO2) in the gas phase. V(m)O(n) clusters are generated by reaction of a laser-generated vanadium plasma with O2 in a supersonic expansion. T...