Reaction of the aryltin(II) hydride {AriPr6Sn(μ-H)}2 (AriPr6 = −C6H3-2,6-(C6H2-2,4,6-iPr3)2) with two equivalents tungsten carbonyl THF complex, [W(CO)5(THF)], afforded divalent tin transition metal W(CO)5{Sn(AriPr6)H}, (1). Complex 1 reacted rapidly ethylene, or propylene under ambient conditions to yield corresponding hydrostannylated organometallic species, W(CO)5{Sn(AriPr6)(Et)} (2), W(CO)5...

The asymmetric unit of the title compound, [Sn(4)(C(7)H(6)Cl)(8)(C(8)H(7)O(2))(2)O(2)(OH)(2)], comprises one-half of the centrosymmetric tin(IV) complex. μ(3)-Oxide and μ(2)-hydroxide bridges link the four five-coordinate Sn(IV) atoms to generate three fused four-membered Sn-O-Sn-O rings in a ladder-like structure. The two endocyclic Sn atoms each bind to two μ(3)-oxide anions and a μ(2)-hydrox...

The title complex, [Sn(4)(C(4)H(9))(8)(C(7)H(3)ClNO(4))(4)O(2)], is a cluster formed by a crystallographic inversion center around the central Sn(2)O(2) ring. Both of the two independent Sn atoms are five-coordinated, with distorted trigonal-bipyramidal SnC(2)O(3) geometries. One Sn atom is coordinated by two butyl groups, one O atom of the benzoate anion and two bridging O atoms, whereas the o...

The Sn(IV) atom in the title salt, [N(CH(3))(3)(C(6)H(5))](2)[SnBr(4)(C(6)H(4)Cl)(2)], exists in a distorted all-trans SnC(2)Br(4) octa-hedral geometry. The Sn(IV) atom lies on a center of inversion. Weak inter-molecular C-H⋯Br hydrogen bonding is observed between trimethyl-phenyl-ammonium cations and the Sn complex anion in the crystal structure.

The first amido-distannyne, L(†)SnSnL(†) (L(†) = -N(Ar(†))(SiPr(i)3), Ar(†) = C6H2{C(H)Ph2}2Pr(i)-2,6,4), has been prepared and shown to possess a very long Sn-Sn single bond; the compound activates dihydrogen under ambient conditions to give L(†)Sn(μ-H)2SnL(†), and reacts with Bu(t)NC to give a stable adduct complex, L(†)(Bu(t)NC)SnSn(CNBu(t))L(†).

A supply network (SN) is a complex adaptive system, and its structure and collaboration mechanism evolves over time. However, most literature views SN as a static system and the study on the evolution of SNs is very limited. Based on complex adaptive system and fitness landscape theory, this paper first proposes an evolution model of SNs in order to understand the general principle of SN evolut...

Fast-scan cyclic voltammetry (CV) and scanning electrochemical microscopy (SECM) were used to investigate the reduction of Sn(IV) as the hexabromo complex ion in a 2 M HBr-4 M NaBr medium. CV at scan rates to 100 V/s and SECM indicated the reaction pathway involves ligand-coupled electron transfer via an ECEC-DISP process: (1) one-electron reduction of Sn(IV)Br6(2-) to Sn(III)Br6(3-); (2) bromi...

[Sn(OSO3)2(TPyHP)](HSO4)2∙8H2O (1), an ionic Sn(IV)-porphyrin complex, was prepared by reacting [Sn(OH2)2TPyP] with dilute sulfuric acid. X-ray structural analysis revealed that the zwitterionic [Sn(OSO3)2TPyHP]2+ species consists of two anionic axial Sn–O–SO3 units and four peripheral pyridinium moieties, overall dicationic charge balanced hydrogen sulfate (HSO4−) counter-anions. Ionic bonding...

In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(4)H(11)Si)(2)], the Sn(IV) ion is coordinated in a distorted tetra-hedral environment formed by two O atoms from two monodenate chloro-acetato ligands and two C atoms from two trimethyl silyl ligands. Two further weak intra-molecular Sn⋯O contacts [2.744 (2) and 2.655 (2) Å] are formed by the chloro-acetato ligands.