Isolated Escherichia coli K-12 cell envelopes or Bacillus subtilis 168 cell walls were reacted with smectite or kaolinite clay in distilled deionized water (pH 6.0); unbound envelopes or walls were separated by sucrose density gradient centrifugation, and the extent of adsorption was calculated. At saturation, both clays adsorbed approximately 1.0 mg (dry weight) of envelopes or walls per mg (d...

Temperature, pressure, and time have been thought to control the smectite-to-illite (S-I) reaction, an important diagenetic process used for petroleum exploration. We demonstrated that microorganisms can promote the S-I reaction by dissolving smectite through reduction of structural Fe(III) at room temperature and 1 atmosphere within 14 days. This reaction typically requires conditions of 300 d...

Slow kinetics is one of the capital issues photocatalytic technology because its heterogeneous nature, which involves multi-step processes. Herein, we show that simple modification sol-gel-based TiO2-smectite composite by hexadecyltrimethylammonium bromide (HDTMA) significantly boosts adsorption and efficient light towards removal diclofenac from water. Three photocatalysts were prepared, inclu...

Recent studies of soil–landscape relationships in northeastern Patagonia identified fibrous-clay minerals in calcic and petrocalcic horizons developed on old fluvio-glacial plains called “Rodados Patagónicos” (RP). The objectives of this study were: i) to evaluate the occurrence of fibrous-clay minerals in the arid soil environment, and ii) to establish the relationship between the soil propert...

This study aims to contribute to a better understanding of the nature and evolution mechanism of interstratifi ed clay minerals. We examined the <2 μm or <0.2 μm size fraction of interstratifi ed kaolinite-smectite (K-S) formed by hydrothermal and hydrogenic alteration of volcanogenic material from a Tortonian clay deposit (Almería, Spain), a weathered Eocene volcanic ash (Yucatan, Mexico), and...

-A high-charge smectite from Arizona [cation-exchange capacity (CEC) = 120 meq/100 g] and a low-charge smectite from Wyoming (CEC = 90 meq/100 g) were used to prepare homoionic tetramethylammonium (TMA)-clay complexes. The adsorption of benzene, toluene, and o-xylene as vapors by the dry TMA-clays and as solutes from water by the wet TMA-clays was studied. The adsorption of the organic vapors b...

-Published chemical data for suites of mixed-layer minerals from diagenetic sedimentary rocks, hydrothermally altered tufts, and a metasomatic bentonite bed indicate that the layer charge and composition of the different components of illite/smectite (I/S) differ from one geological environment to another. It appears that the composition of the elemental smectite and illite layers in the I/S is...