The leaching kinetics of smithsonite ore in acetic acid solutions, an environmental friend, and natural reagent was investigated. The influence of parameters such as reaction temperature, particle size, solid-liquid ratio and acid concentration was studied in order to reveal the leaching kinetics of smithsonite ore. In this study, experimental and statistical methods were carried out in order t...

Gold nanorods (AuNR) have been intensively used in nanomedicine for cancer diagnostics and therapy, due to their excellent plasmonic photothermal properties. Tuning the size and aspect ratio of AuNR tailors the localized surface plasmon resonance (LSPR) in the NIR spectrum at which biological tissues are transparent, thus enables specific and effective treatment. The AuNR extravasates into tumo...

Calcium carbonate is a versatile mineral with diverse industrial applications. Drying is a necessary processing step in preparation of calcium carbonate product. Deep knowledge of drying kinetics is required in order to design an appropriate dryer. The main aim of the present study was to investigate the drying kinetics of calcium carbonate, experimentally. Thirteen empirical correlations with ...

A method for forward and inverse integration of a class of population balance equations with a size-dependent growth rate is contributed in this article. A unique differential transformation of the independent time and internal coordinates is introduced, leading to straight line characteristics with constant values for the density function. The evolution of the density function is then given by...

The property of DNA is strongly influenced by counterions. Packing a dense layer of DNA onto a gold nanoparticle (AuNP) generates an interesting colloidal system with many novel physical properties such as a sharp melting transition, protection of DNA against nucleases, and enhanced complementary DNA binding affinity. In this work, the effect of monovalent cation size is studied. First, for fre...

Combining scanning tunneling microscopy (STM), IR reflection absorption spectroscopy (IRAS) and molecular beam (MB) techniques, we have investigated particle size effects on a Pd/Fe(3)O(4) model catalyst. We focus on the particle size dependence of (i) CO adsorption, (ii) oxygen adsorption and (iii) Pd nanoparticle oxidation/reduction. The model system, which is based on Pd nanoparticles suppor...

The magnetic-field-dependent kinetics of geminate radical pairs, created by electron transfer from aniline fo rhionine triplet in reversed micelles has been studied by nanosecond laser flash spectroscopy. Dependin, = on the water concentration, the rate constant of intrarnicek recombination is reduced by a factor between 2.4 and 3.2 in a field of 1 T. The B,, values increase from about 15 to 48...

In situ high-temperature (T(a)=1050-1250 K) scanning tunneling microscopy was used to determine the coarsening and decay kinetics of two-dimensional TiN adatom and vacancy islands on atomically smooth TiN(111) terraces. We report the first observation of an abrupt decrease in decay rates, irrespective of T(a), of adatom islands with areas less than a critical value of 1600 A(2). However, no dec...