In this work, the effects of strontium addition on the structure and optical properties of nanostructured bismuth silicate (Bi4Si3O12) thin films prepared via sol-gel were studied. At first, different sols containing the optimum ratio of precursors were synthesized, and then, the prepared sols were coated on the substrate via dip coating. The dip coated samples were dried at 100oC and, in order...

Sol-gel derived silica possess many promising features, including low-temperature preparation procedure, porosity, chemical and physical stability. Applications exploiting porous materials to encapsulate sensor molecules, enzymes and many other compounds, are developing rapidly. In this paper some potential applications, with emphasis on biomedical and environmental ones, are reviewed. The mate...

The racemic hexacoordinate silicon(IV) complex tri(n-butyl)ammonium bis[citrato(3-)-O1,O3,O6]silicate (1) was synthesized by treatment of Si(OMe)4 with 2 molar equiv of citric acid and 2 molar equiv of N(n-Bu)3. The corresponding germanium analogue, tri(n-butyl)ammonium bis[citrato(3-)-O1,O3,O6]germanate (5; structurally characterized by single-crystal X-ray diffraction), was obtained analogous...

This work presents a novel method for direct desorption/ ionization of analytes from sol-gel-derived film. 2,5-Dihydroxy benzoic acid (DHB), a common MALDI matrix, was incorporated into a sol-gel polymeric structure. The sol-gel-derived DHB thin film can assist the mass analysis of analytes by laser desorption/ionization, with a matrix interference-free background in the mass spectra. The sol-g...

A new concept of critical point is expounded by analysing the potentiometric titration curves of aluminium salt solutions under the moderate slow rate of base injection. The critical point is defined as the characteristic spot of the Al salt solutions potentiometric titration curve, which is related to the experiment conditions. In addition, the changes of critical points reflect the influence ...

sol-gel and polymeric membrane electrodes, based on thiacalix[4]arene as a neutral carrier, weresuccessfully developed for the detection of vo2+ in aqueous solutions. the sol-gel and pvcmembrane electrodes exhibited linear response with nernstian slopes of 29.3 and 28.4 mv perdecade, respectively, within the vanadyl ion concentration ranges from 1.0 × 10-6 to 1.0 × 10-1mol dm-3 and from 1.0 × 1...

in this research zinc oxide (zno) nano-crystalline powders were prepared by sol-gel method using zinc acetate. the zno nanoparticles were characterized by x-ray diffraction (xrd), scanning electron microscopy (sem), ultraviolet-visible (uv-vis), fourier transform infra-red (ft-ir) and energy dispersive x-ray (edx) spectroscopy. the structure of nanoparticles was studied using xrd pattern. the c...

beryllium  oxide  (beo)  nanopowder  was  synthesized  using  sol-gel method  and  the  effects  of  changes of  chemical  reagents  were investigated.  because  of  tissue  equivalence  and  other  outstanding thermoluminescence  (tl) properties of  the bulk material  in x and γ dosimetry, the applicability of this nanostructure in tl dosimetry was studied  following  irradiation to  the 137 c...