The mechanism for the photochemical isomerization reaction is investigated theoretically using a model system of a five-membered-ring silene and the CAS(8,8)/6-311G(d) and MP2-CAS-(8,8)/6-311++G(3df,3pd)//CAS(8,8)/6-311G(d) methods. These model investigations indicate that the preferred reaction route for a five-membered-ring silene, which leads to the photorearrangement product, is as follows:...

Two intramolecularly donor-stabilized silenes, l-(8-dimethylamino-l-naphthyl)-l,2,2-tris(trimethylsilyl)silene (1 ), and l-[bis-2 ,6 -(dimethylaminomethyl)phenyl]-l,2 ,2 -tris(trimethylsilyl)silene 2, were studied by 2 9 Si and C NMR spectroscopy, using polarization transfer techniques in order to determine coupling constants V (2 9 Si,2 9 Si) in = 1,2, 3) and '/ ( 2 9 Si,l3 C) together with is...

The theory of solution for quantum field functional equations is developped for a suitable testproblem of quantum mechanics. In Sect. 1 the functional formulation of the anharmonic oscillator in its spinorial representation is given, and in Sect. 2 translational equivalent functional equations are discussed. The expansion of the physical state functionals into series of basefunctionals and the ...

Chiral Symmetry is important in a lot of situations. In this talk I will restrict myself to consequences of Chiral Symmetry for the strong interaction. The subject is very broad as can be judged from the lectures and review articles. In its modern form it was founded by Weinberg and Gasser and Leutwyler. I will discuss a few of the basics in sects. 2, 3, 4. The applications to ππ scattering (se...

Plant-insect interactions often are important for plant reproduction, but the outcome of these interactions may vary with environmental context. Pollinating seed predators have positive and negative effects on host plant reproduction, and the interaction outcome is predicted to vary with density or abundance of the partners. We studied the interaction between Silene stellata, an herbaceous pere...

This chapter first provides a formulation of the geometric path planning problem in Sect. 5.1 and then introduces sampling-based planning in Sect. 5.2. Sampling-based planners are general techniques applicable to a wide set of problems and have been successful in dealing with hard planning instances. For specific, often simpler, planning instances, alternative approaches exist and are presented...

This chapter first provides a formulation of the geometric path planning problem in Sect. 7.2 and then introduces sampling-based planning in Sect. 7.3. Sampling-based planners are general techniques applicable to a wide set of problems and have been successful in dealing with hard planning instances. For specific, often simpler, planning instances, alternative approaches exist and are presented...

BACKGROUND Dual energy CT (DECT) has proven its potential in oncological imaging. Considering the repeated follow-up examinations, radiation dose should not exceed conventional single energy CT (SECT). Comparison studies on the same scanner with a large number of patients, considering patient geometries and image quality, and exploiting full potential of SECT dose reduction are rare. Purpose of...