Fourteen novel silane coupling agents with a quaternary ammonium group introduced into the molecule, [CH(2)=CHCH(2)N(+)(CH(3))(C(n)H(2n+1))(CH(2))(3)Si(OCH(3))(3)]X(-) (n-X, n=10-18, X=Cl, Br, or I), were synthesized with the aim of using these agents to make material surfaces antimicrobial for a long period of time. Measurements of the minimum inhibitory concentrations (MIC) against 12 kinds o...

The reactivity of immobilized functional groups in thin layers of (3-aminopropy1)triethoxy~ilane (APS), (3-mercaptopropyl)trimethoxy~ilane, (3-bromopropyl)trimethoxysilane, and (8-bromoody1)trimethoxysilane on oxidized aluminum substrates was studied with reflection-adsorption infrared spectroscopy (RAIR), optical ellipsometry and contact-angle measurements. Mass changes on the surface associat...

background: bonding of molar tubes is becoming more popular in orthodontics. occasionally, these bonding are done on posterior porcelain crowns or bridges. the purpose of this study was to evaluate the shear bond strength of buccal tubes on feldspathic porcelain crowns with two different methods. materials and methods: forty porcelain right molar crowns were fabricated for this study. the crown...

objective: repair of an indirect restoration is usually preferred over its replacement. this study aimed to evaluate the effect of silane in different surface preparation techniques on the bond strength of direct to indirect composite resin.   methods: for this in vitro experimental study, 48 indirect composite cubes were fabricated, divided into 4 groups of 12 and subjected to the following pr...

BACKGROUND AND OBJECTIVES Acrylic resin ruled the dental profession for 60 years, and this success is attributed to its aesthetics, handling properties, physical and biological compatibility, its stability in oral environment and its cost effectiveness. The objective of this study is to evaluate and compare the bond strength of acrylic resin teeth treated with various conditioning materials lik...

The objective of this study was to investigate the rebonding effect of a new silane coupling agent on various ceramic brackets bonded to ceramic specimen. Different ceramic brackets (Fascination 2, Clarity SL, and In-OvationC) were assigned to three groups: rebonding with new silane coupling agent, rebonding with conventional silane coupling agent, or regular bonding as control (n = 16). Bracke...

A simple method for the synthesis of new bio-based silane coupling agents (SCAs) with a terpene aromatic core by functionalization cheap, natural eugenol and its sulfur derivatives using hydrosilylation C=C bonds HSi(OEt)3, followed nucleophilic substitution reactions OH/SH groups is presented. The obtained alkoxysilanes possess different polymer-reactive functionalities (alkenyl, epoxide, thii...