The NMR signals of 113Cd have been observed in powder samples of the cadmium halides CdF,, CdCl2, CdBr2 '4H20, Cdl 2 , of the cadmium chalcogenides CdO, CdS, CdSe, CdTe and of CdC03 . For m C d in CdCl2 , CdBr2-4H20, CdS and in CdSe anisotropics of the nuclear magnetic shielding have been detected. The shielding tensor in these powders is axially symmetric. For the other specimens no anisotropi...

Nuclear magnetic shielding is a second-order molecular electronic property which provides a severe test of the accuracy of molecular quantum mechanical calculations. While electric dipole polarizability and hyperpolarizabilities provide tests of the wavefunction at the outer regions, nuclear shielding is very sensitive, especially to contributions from high angular momentum functions, in the re...

The nuclear magnetic shielding tensor is a sensitive probe of the local electronic environment, providing information about molecular structure and intermolecular interactions. The magnetic shielding tensor of the water proton has been determined in hexagonal ice, but in liquid water, where the tensor is isotropically averaged by rapid molecular tumbling, only the trace of the tensor has been m...

Progress of the shielding calculation of the Super-FRS is reported here. At least as important as the shielding of the target area is the determination of the shielding in the region of the first dipoles as the part of the primary beam that will not interact in the target will be stopped here. The Monte-Carlo-method with FLUKA [1] used for the shielding assessment here has already been describe...

Using solid state multiple pulse techniques the magnetic shielding tensors a of the F nuclei in a single crystal of KZnF 3 have been measured. The F~-site symmetry in KZnF3 , D 4 h , allows axial anisotropy of a and determines fully the principal shielding directions. Using CaF 2 as the reference compound, the average shielding is + 85 ppm and the shielding anisotropy is + 18.4 ppm. These resul...

This article presents some new experimental data for study the shielding effect of electromagnetic wave. The frequencies of electromagnetic wave are mainly focused on emission of daily electrical equipments, which are normally called “low frequency electromagnetic waves”. In this work, a water pump with maximum magnetic field intensity of ca. 2300 mG was applied as emission source of the electr...

PURPOSE To evaluate the cumulative dose at point A for three and four centimeters central shielding. MATERIAL AND METHODS The plans of external beam radiotherapy plus conventional intracavitary brachytherapy were performed. Three or four centimeters central shieldings (after 44 Gy) were applied to the standard whole pelvis irradiation. Additional intracavitary brachytherapy 4 × 7 Gy at point ...

Gas-phase multinuclear magnetic resonance (MR) spectra allow the total elimination of intermolecular effects from magnetic shielding in molecules. Consequently, the resonance frequencies of isolated atoms and molecules are also available for reading from MR spectra. Following the connectivity between nuclear magnetic moments, resonance frequencies of two different nuclei in the same MR experime...