The efficient loading and sustained release of proteins from bioactive microspheres remain a significant challenge. In this study, we have developed bioactive microspheres which can be loaded with protein and then have a controlled rate of protein release into a surrounding medium. This was achieved by preparing a bioactive microsphere system with core-shell structure, combining a calcium silic...

In this paper, yolk-shell hollow nanospheres of amorphous calcium phosphate (ACP) are prepared, and its loading capacity is investigated by comparing with that of solid-shell hollow structure ACP and cage-shell hollow structure ACP. Results show that the products are yolk @ cage-shell of ACP with large shell's pores size (15-40 nm) and large cavity volume. Adsorption results show that the loadi...

The magnetite (Fe3O4) nanoparticle and graphene oxide (GO) have  become interesting materials due to their advanced applications. In this work, we investigated the fabrication of Fe3O4 nanoparticles (NPs) from iron sands and reduced graphene oxide (rGO) NPs from natural graphite. The core-shell fabrication of the Fe3O4/rGO was co...

A new structure, consisting of a shell cross-linked, 2 nm size siloxane nanocage containing propylamine groups tethered to the interior face of the shell was synthesized, starting with micelles of the surfactant molecule, (triethoxysilyl)propylcetylcarbamate. After hydrolysis of the ethoxysilyl groups and condensation and capping of the silanols to form a cross-linked, one-atom-layer-thick silo...

We present a general strategy to synthesize uniform MnCo2O4 submicrospheres with various hollow structures. By using MnCo-glycolate submicrospheres as the precursor with proper manipulation of ramping rates during the heating process, we have fabricated hollow MnCo2O4 submicrospheres with multilevel interiors, including mesoporous spheres, hollow spheres, yolk-shell spheres, shell-in-shell sphe...

It is well known that gold cluster can have planar or hollow cagelike structure due to the relativistic effect. In this study, by first principles calculation on the Au(58) cluster, we propose that gold cluster of medium size can form a shell-like structure, which is demonstrated by the remarkable robustness of a double shell structure with a hollow inner shell of ten atoms.

In order to implement an integrated optical quantum circuit, designing waveguides based on the quantum box is of prime importance. To do this we have investigated optical waveguide both with and without optical pumping. The rate of absorption and emission using an array of AlGaAs/GaAs quantum box core/shell structure in the optical waveguide with various pumping intensities has computed. By con...

The photocatalytic coatings were prepared via incorporating the modified titania nanoparticles into epoxy-based inorganic-organic hybrid coatings. Titania nanoparticles were first synthesized from tetra-n-butyl titanate using sol-gel methods by two different calcination treatments, i.e., in mild condition (80°C) and 500°C. The formed anatase nanoparticles were further modified as Titania-Silica...

The photocatalytic coatings were prepared via incorporating the modified titania nanoparticles into epoxy-based inorganic-organic hybrid coatings. Titania nanoparticles were first synthesized from tetra-n-butyl titanate using sol-gel methods by two different calcination treatments, i.e., in mild condition (80°C) and 500°C. The formed anatase nanoparticles were further modified as Titania-Silica...

We study off-shell effects of the pion cloud on the sea quark distribution in the nucleon. The structure function of the off-mass-shell pion is obtained within the Nambu and Jona-Lasinio model, where the shape of the distribution function depends on the pion momentum. By using the momentum dependent pion structure function, the SU(2) flavor asymmetry in the nucleon see is reexamined within the ...