A variety of hydrofluorocarbon (HFC) compounds, both as pure substances and mixtures, are being developed as alternative refrigerants to replace the exsting chlorofluorocarbons and hydrofluorocarbons which have been linked to stratospheric ozone depletion. The use ofHFC's in refrigeration systems will require new lubricants, and polyolesters are being widely promoted as the lubricant of choice ...

An analytical equation of state by Song and Mason is developed to calculate the PVT properties ofmercury. The equation of state is based on the statistical-mechanical perturbation theory of hard convexbodies and can be written as a fifth-order polynomial in the density. There exists three temperaturedependentparameters in the equation of state; the second virial coefficient, an effective molecu...

The impact of man-made chemicals on the environment, and in particular, the ozone layer, has been investigated over the last 20 years. The phaseout of CFCs under European Regulations and the Montreal Protocol has already taken place and HCFCs are set to follow. A wide range of alternative refrigerants with zero ozone depletion potential have already been developed as replacements for the refrig...

A second virial coefficient correlation suitable for two different temperatures ranges, (T*)-2£180 and (T*)-2>180, where T* is RT/DHvap is presented. The equation of state can be calculated for different, complicated non-polar, and slightly polar liquid mixtures at any temperature over the range from Ttp to T<su...

This paper presents a study on the thermodynamics and transport properties of hot potassium carbonate aqueous system (HPC) using electrolyte non-random two liquid, (ELECNRTL) model. The operation conditions are varied to determine the system liquid phase stability range at the standard and critical conditions. A case study involving 30 wt% K2CO3, H2O standard system at pressure of 1 bar and tem...

In consideration of physical and chemical properties of pure substances, speed of sound is one of important quantity which can used to calculate many of other thermo-physical properties such as isothermal compressibility, Joule-Thomson coefficient, isobaric heat capacity and etc. These thermo-physical properties are the main parameters in industrial and chemical processes. Development of accura...

Abstract Due to the phase-out of CFCs and HCFC refrigerants, propane is a nature refrigerant occurring substance produced by natural gas production oil refining. As result, has higher latent heat lower density than conventional refrigerants while maintaining comparable saturation pressure thermal conductivity. So, already widely used in domestic fridges freezers for many years. However, propane...

The present paper summarizes the activities at LTT-Erlangen on the field of thermophysical properties research for pure refrigerants and refrigerant mixtures. For the characterization of their thermophysical properties dynamic light scattering (DLS) has been intensively applied as a key tool during the past two decades. Beside a representation of the essential features of DLS for the determinat...

a second virial coefficient correlation suitable for two different temperatures ranges, (t*)-2£180 and (t*)-2>180, where t* is rt/dhvap is presented. the equation of state can be calculated for different, complicated non-polar, and slightly polar liquid mixtures at any temperature over the range from ttp to tc and up to high pressures. the latent heat of vaporization and density at the triple p...