We have recorded high resolution, partially rotationally resolved, jet-cooled cavity ringdown spectra of the origin band of the A-X electronic transition of both the G and T conformers of the perproteo and perdeutero isotopologues of the ethyl peroxy radical, C(2)H(5)O(2). This transition, located in the near infrared, was studied using a narrow band laser source (< or approximately 250 MHz) an...

Rotationally resolved nonresonant two-photon mass analyzed threshold ionization ~MATI! and zero kinetic energy ~ZEKE! photoelectron spectra of CH2CO 1 and CD2CO 1 are reported. The spectra are dominated by the origin band and totally symmetric a1 vibrations, n4 ~C5C symmetric stretch! and n2 ~C5O asymmetric stretch! for CH2CO , and n1 ~C5O asymmetric stretch!, n3 ~C5C symmetric stretch!, and n4...

An equilateral-triangular shape of three alpha clusters surrounded by excess neutrons is suggested for 14C, based on the molecular-orbit model. It is found that the attractive interaction between an excess neutron and an alpha particle stabilizes the K(pi)=0(+) and 3(-) rotational bands, which demonstrates an equilateral-triangular symmetry. This K(pi)=3(-) band at 3 MeV below the 10Be+alpha th...

Voltage-induced infrared spectra of annealed spin-cast thin films of ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF-TrFE)) (molar ratio, 3:1) were measured in a stepwise cyclic external electric field. Most of the observed infrared bands originated from the β ferroelectric crystalline phase. The voltage-induced spectral changes were decomposed into zeroth- (original), first...

The infrared emission spectra of a hydrogen flame and' of a natural gas flame have been compared in the region from 1. 7p. to 24p.. Emission bands have been observed at 1.87p., 2.78p. , 4.37p., 6.20p., and 15p. that a re produced by molecules of H 20 and CO2• Another band at 3.316p. is attributed to methane. From 3.0p. to 3.8p. there are a number of rotational lines, some of which may be produc...

Methyl chloride is of interest for atmospheric applications, since this molecule is directly involved in the catalytic destruction of ozone in the lower stratosphere. In a previous work [Bray et al. JQSRT 2011;112:2446], lines positions and intensities of self-perturbed CH3Cl and CH3Cl have been studied into details for the 3.4 μm spectral region. The present work is focused on measurement and ...

Combining recent and new inelastic neutron scattering data for the molecular cyclic cluster Cr8 produces a deep understanding of the low lying excitations in bipartite antiferromagnetic Heisenberg rings. The existence of the L band, the lowest rotational band, and the E band, essentially spin wave excitations, is confirmed spectroscopically. The different significance of these excitations and t...

Quantum electrodynamic effects have been systematically tested in the progression of rotational quantum states in the X 1Σ(g)(+), v=0 vibronic ground state of molecular hydrogen. High-precision Doppler-free spectroscopy of the EF 1Σ(g)(+)-X 1Σ(g)(+) (0,0) band was performed with 0.005  cm(-1) accuracy on rotationally hot H2 (with rotational quantum states J up to 16). QED and relativistic contr...

Band mixing calculations in rapidly rotating well-deformed nuclei are presented, investigating the properties of energy levels and rotational transitions as a function of excitation energy. Substantial fragmentation of E2 transitions is found for Ex > ∼ 800 keV above yrast, which represents the onset of rotational damping. Above Ex ≈ 2 MeV, energy levels and E2 strengths display fluctuations ty...