A Simple and efficient method for Michael addition of pyrrole and indole to α,β- un saturated compounds has been developed in the presence of oxalic acid under refluxing reaction condition was achieved.

Dye sensitized solar cells have achieved more than 12% efficiency[1][2] since 1991 when first metal organicphotosensitizer was made by Gratzel based on ruthenium complex[3].Here we discussed the effect ofextended conjugation absorption spectra of photosensitizers[4]. The designed dye molecules are ondonor- π -acceptor model. dyes named as S1 [naphthalene-pyrrole-butanoic acid] and S2[naphthalen...

The title compound, C(21)H(27)N(7), was synthesized by reaction of tris-(2-amino-ethyl)amine and pyrrole-2-carbaldehyde in ethanol at room temperature. The structure is stabilized by intra- and inter-molecular C-H⋯N and N-H⋯N hydrogen-bonding inter-actions.

5-Substituted dipyrromethanes are important precursors for the synthesis of meso-substituted porphyrins,1 expanded porphyrins, and porphyrin analogues.2 Several one-flask methods have been reported for the synthesis of 5-substituted dipyrromethanes by the condensation of an aldehyde and pyrrole using various combinations of acids and solvents.3-14 We previously reported a one-flask synthesis of...

Aerobacter aerogenes, Paracolobactrum aerogenoides, Spirillum serpens, and gelatinous strains of Chromobacterium violaceum produced an extracellular, ether-soluble, Ehrlich-positive substance when grown in media prepared with gelatin hydrolysate. The substance has been tentatively identified as pyrrole-2-carboxylic acid. Both hydroxy-l-proline and allo-d-hydroxyproline have been shown to be pre...

Carbon catalyst consisting of a hybrid structure made up of amorphous carbon and nanographite was prepared from the leaves of Pinus Roxburghii. The catalyst was prepared through sodium hydroxide and hydrochloric acid treatment of the dried pine leaves; and further functionalized with sulfuric acid treatment to incorporate the acidic functionalities. The synthesized catalyst was characterized by...