Self-consistent periodic slab calculations based on gradient-corrected density functional theory (DFT-GGA) have been conducted to examine the reaction network of propane dehydrogenation over close-packed Pt(111) and stepped Pt(211) surfaces. Selective C-H or C-C bond cleaving is investigated to gain a better understanding of the catalyst site requirements for propane dehydrogenation. The energy...

In this article, experimentally determined values of sound velocity in LPG in a temperature range (–23...+55) °C are presented. The measurements were taken using two industrial LPG samples in a standard five liter pressurized gas tank. The propagation time of a ultrasonic signal with the frequency of 0.7 MHz was measured. To increase the accuracy of measurement, a pulse-phase method was applied...

Measurements of the times of arrival of the primary shock produced by the explosion of a nominal 20 tn propane–oxygen mixture have been analysed to provide the variation of the peak hydrostatic overpressure as a function of distance. The results have been scaled to those for a charge of unit mass at normal temperature and pressure, based on the masses of the propane and oxygen and of the propan...

Introduction Conclusions References Tables Figures Back Close Print Version Interactive Discussion

The kinetics of hydrogen exchange between the molecules of propane-d8, propane-1,1,1,3,3,3-d6, propane-2,2-d2, and Brönsted acid sites of the zeolite H-ZSM-5 have been monitored in situ by 1H MAS NMR spectroscopy in the temperature range of 230–280 ◦C. The intramolecular hydrogen transfer was estimated by in situ 13C MAS NMR spectroscopy of the kinetics of 13C-label scrambling in adsorbed propa...

Long-lived spin states of hyperpolarized propane-d6 gas were demonstrated following pairwise addition of parahydrogen gas to propene-d6 using heterogeneous parahydrogen-induced polarization (HET-PHIP). Hyperpolarized molecules were synthesized using Rh/TiO2 solid catalyst with 1.6 nm Rh nanoparticles. Hyperpolarized (PH ∼ 1%) propane-d6 was detected at high magnetic field (9.4 T) spectroscopica...

"Burn-like" propane thermal injury is produced by evaporative heat loss causing damage to vital structures. Acute appearance is that of heat burn with progressive vascular compromise. Histopathologic study demonstrates epidermal and dermal necrosis followed by vascular thrombosis. Physicians should be aware of this injury and its consequence in light of the widespread use of pressurized propane...

Biologically activated carbon (BAC) can be used in both municipal water and hazardous waste remediation applications to enhance contaminant attenuation in water; however, questions remain about how selective pressures can be applied to increase the capabilities of microbial communities to attenuate recalcitrant contaminants. Here we utilized flow-through laboratory columns seeded with municipal...

An in situ co-metabolic air sparging (CAS) study was carried out at McClellan Air Force Base (MAFB), Sacramento, CA, USA, in a trichloroethene- (TCE) and cis-dichloroethene (cis-DCE)-contaminated aquifer where one test zone received 2% propane in air and the other served as a control and received only air. As part of that study, bacterial population shifts were evaluated by length heterogeneity...