Hydrate phase equilibria for the binary CO2+water and CH4+water mixtures in silica gel pore of nominal diameters 6, 30, and 100 nm were measured and compared with the calculated results based on van der Waals and Platteeuw model. At a specific temperature, three-phase hydrate-water-vapor (HLV) equilibrium curves for pore hydrates were shifted to the higher-pressure condition depending on pore s...

this paper presents the results of a series of monotonic and post-cyclic triaxial tests carried out on a clay specimen and three types of clay-sand mixed specimens. the focus of the paper is on the post-cyclic mechanical behavior of the mixed specimens, as compared to their monotonic behavior. analyses of the tests results show that cyclic loading degrade undrained shear strength and deformatio...

We evaluated the effectiveness of Ambersorb, a carbonaceous resin, in reducing bioavailability of polycyclic aromatic hydrocarbons (PAHs) in contaminated sediments collected from the field. In laboratory studies, sediment pore-water concentrations of eight unsubstituted PAHs were significantly decreased after resin addition. Reduced PAH concentrations in oligochaete tissues from a laboratory bi...

The geochemical composition of sediment pore water was investigated in comparison with the composition of sediment particles and surface water in an estuary within one of the most industrialized areas in Latin America (Santos-Cubatão estuarine system, SE Brazil). Pore and surface waters presented anomalously high levels of F(-), NH4(+), Fe, Mn and P due to two industrial point sources. In the s...

Chitosan/polyethersulfone (CS/PES) composite membrane was prepared from casting chitosan solution on polyethersulfone substrate membrane. The Substrate membrane was prepared by phase inversion technique using polyethersulfone (PES) and dimethylacetamide (DMAc) as solvent with and without the addition of polyvinylpyrrolidone (PVP) as pore-forming agent. The effects of the composition of the c...

Fig. 1. Behavior of condensates on smooth surfaces and within pores. The surface wettability determines the contact angle θ and the curvature of a liquid condensate on a smooth surface (A) and within a pore (B), where θ and the pore diameter strongly affect the liquid’s vapor pressure (C), here for the case of liquid water. Capillary condensation of a liquid (red) and subsequent crystal (green)...

Polycarbonate Nuclepore filters are better than cellulose filters for the direct counting of bacteria because they have uniform pore size and a flat surface that retains all of the bacteria on top of the filter. Although cellulose filters also retain all of the bacteria, many are trapped inside the filter where they cannot be counted. Before use, the Nuclepore filters must be dyed with irgalan ...

Water plays a key role in biological membrane transport. In ion channels and water-conducting pores (aquaporins), one-dimensional confinement in conjunction with strong surface effects changes the physical behavior of water. In molecular dynamics simulations of water in short (0.8 nm) hydrophobic pores the water density in the pore fluctuates on a nanosecond time scale. In long simulations (460...

In living cells specialized water channels, the glycero-aquaporins, are responsible for rapid passive transport of water through the membrane. Crystal structures showed that these protein pores have diameters comparable to the size of a single water molecule (around 0.3 nm) and lengths around 2 to 3 nm. Despite being strongly confined, water moves rapidly through these and other narrow peptide ...