Soluble polymer-supported chemistry is a technology that allows the blending of the benefits of polymer-supported synthesis and solution-phase chemistry. Herein, we describe our recent efforts in this area targeted at exploring the scope of poly(ethylene glycol) (PEG) as the matrix. Specifically we describe the use of PEG as a support for triphenyl phosphine and for the Stille reaction.

It is widely appreciated that an attractive polymer-substrate interaction can slow relaxation in thin supported polymer films and polymer nanocomposites. Recent measurements and simulations on nancomposites have indicated that this slowing of polymer dynamics occurs more strongly near a highly attractive particle surface where a "bound" layer having a much lower mobility can form, strongly infl...

a floating polymer-supported photocatalyst based on polystyrene impregnated with titaniumdioxide particles was developed using a facile solvent-cast method at ambient temperature. the preparedphotocatalysts were characterized by x-ray diffraction, scanning electron microscopy and fourier transforminfrared spectroscopy. the photocatalytic activity of the developed photocatalysts was investigated...