Proton exchange membranes (PEMs) play an important role in the fuel cell systems. A good PEM must meet a series of requirements such as high proton conductivity, excellent mechanical strength and stability, chemical and electrochemical stability, low fuel crossover, etc. Nafion is currently the most commercially utilized electrolyte membranes for polymer electrolyte fuel cells, with high chemic...

Solid polymer electrolytes have been prepared by solution casting technique. Carboxy methylcellulose (CMC)-ammonium nitrate (AN) films were studied with varied AN salt concentration from 5-50 wt.% at ambient temperature. X-ray diffraction (XRD) pattern shows the amorphous nature of polymer electrolyte samples. IR-spectra confirm the polymer-salt complexes in the range of 1633 829 cm -1 . Impeda...

Single-particle fluorescence spectroelectrochemistry was used to investigate the electrochemical oxidation of isolated, immobilized particles of the conjugated polymers BEH-PPV and MEH-PPV at an indium tin oxide (ITO) electrode immersed in an electrolyte solution. Two types of particles were investigated: (i) polymer single molecules (SM) and (ii) nanoparticle (NP) aggregates of multiple polyme...

The electrochemical properties of a solid polymer electrolyte consisting of a diblock copolymer and lithium bis oxalato borate, LiBC4O8 LiBOB salt, is reported. The spherical microphase-separated diblock copolymer is composed of a majority poly ethylene oxide PEO block and a minority random copolymer block of methyl methacrylate MMA and lithium salt of methacrylic acid MAALi , PEO-bPMMA-ran-PMA...

While much energy storage research focuses on the performance of individual components, such as the electrolyte or a single electrode, few investigate the electrochemical system as a whole. This research reports on the design, composition, and performance of a Zn/MnO2 battery as affected by the manufacturing method and next-generation gel polymer electrolyte composed of the ionic liquid [BMIM][...

Novel ionic liquid polymer electrolytes based on polymer poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP), lithium bis(tri-fluoromethanesulfonyl)imide (LiTFSI) with different 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (EMITFSI) weight ratios have been synthesized and applied to quasi-solid state Li–air batteries. The morphology, electrochemical properties of prepa...

High ionic conductivity solid polymer electrolyte (SPE) has long been desired for the next generation high energy and safe rechargeable lithium batteries. Among all of the SPEs, composite polymer electrolyte (CPE) with ceramic fillers has garnered great interest due to the enhancement of ionic conductivity. However, the high degree of polymer crystallinity, agglomeration of ceramic fillers, and...

Graphite oxide was synthesized from natural flake graphite by the modified Hummers method. In brief, 200 mg of Graphite particles were immersed in Concentrated sulfuric acid (46 ml) and KMnO4 (6 g) was added slowly in small quantities in which temperature was maintained between the 0 and 5 c using an ice bath, after the complete oxidation of KMnO4, the mixture was heated to 37 c and kept at thi...

A polymer film electrode can be defined as an electrochemical system in which at least three phases are contacted successively in such a way that between a first-order conductor (usually a metal) and a second-order conductor (usually an electrolyte solution) is an electrochemically active polymer layer. The polymer layer is more or less stably attached to the metal, mainly by adsorption (adhesi...

Nitroxide polymer brushes were covalently patterned on flexible conducting substrates via surface-initiated atom transfer radical polymerization and microcontact printing. As a cathode of organic radical batteries, the nitroxide polymer brushes prevent the nitroxide polymer from dissolving into electrolyte solvents, which improves the cycle-life performance of batteries.