The complex (η(5)-C(5)H(5))Ir(η(4)-C(6)H(6)) reacts with Grubbs' catalyst to give a novel polyacetylene consisting of cyclopentadienyliridium bound s-cis butadiene moieties separated by C=C linkages. A crystal structure of the pentamethylcyclopentadienyl analog establishes a strong structural analogy with norbornadiene, a classical ROMP monomer.

We report the dual memory of both the enantiomeric right- and left-handed helical conformations induced in a polyacetylene based on the temperature-stimulated helicity inversion of the polymer. The polyacetylene folds into a one-handed helix induced by noncovalent bonding interactions with a single enantiomeric amine. The induced helix underwent a reversible inversion of the helicity by tempera...

We studied the excitation dynamics in films of disubstituted polyacetylene, a degenerate groundstate conjugated polymer, using psec transient and steady-state spectroscopies. The polymer is found to support charged and neutral topological soliton excitations concurrent with a strong intrinsic photoluminescence band with quantum efficiency, h . 50%. This leads to stimulated emission in thin film...

2014 Photovoltaic devices have been obtained by a direct polymerization of undoped (or p-type doped) thin film (CH)x layer onto a polycrystalline cadmium sulfide film. The morphology of the contact is observed by S.E.M. microscopy. The electrical characteristics of this device are studied in the dark or under illumination. The main result, at AM1, 100 mW/cm2 with doped (CH)x correspond to 0.5 p...