A comparison of the photoefficiency of Ni(II) and NiS incorporated into zeolite P towards photodecolorization of Eriochrome Black T dye solution was investigated in a photocatalytic reactor using UV lamp as a light source. The effect of various experimental variables on the decolorization performance of the process was evaluated by examining catalyst dosage, temperature, initial dye concentrati...

OBJECTIVE The objective of this study was to develop and validate a simple method for estimation of tramadol hydrochloride (TH) in pure and pharmaceutical dosage forms using a colorimeter. MATERIALS AND METHODS TH on reaction with Eriochrome Black T in the presence of acetate buffer at pH 3.5 forms a colored complex. This complex was extracted with a fixed volume of chloroform. The optical de...

A stable electroactive thin film of poly(caffeic acid) has been deposited on the surface of a glassy carbon electrode by potentiostatic technique in an aqueous solution containing caffeic acid. The voltammetric behavior of epinephrine (EP) at the poly(caffeic acid) modified glassy carbon electrode was studied by cyclic voltammetry. The poly(caffeic acid) modified electrode exhibited a promotion...

A novel polymer modified electrode is discussed in this paper. This resulting electrode can catalyze remarkably toward the electrochemical oxidations of dopamine (DA) and ascorbic acid (AA). Moreover, it can clearly discriminate the electrochemical oxidations of DA from that of AA based on their semi-derivative voltammograms. Hence, a simultaneous determination of DA and AA based on semi-deriva...

in this work, spherical pt nanometer-scale particles supported on the poly (m-toluidine)/triton x-100 film modified carbon nanotube paste electrode (pt/pmt (tx-100)/mcntpe) was used as a potent catalyst for electrooxidation of formaldehyde (hcho) in both 0.5 m h2so4 and 0.1 m naoh solutions. the obtained results showed that utilization of tx-100 as an additive during the electropolymerization p...

Poly 8-(3-acetylimino-6-methyl-2,4-dioxopyran)-1-aminonaphthalene (PAMDAN) films were electrodeposited on platinum electrode (Pt), forming PAMDAN/Pt modified electrode, to study its utility in electrooxidation of iodide ion. The electrooxidation process was investigated by cyclic voltammetry. The effects of different factors e.g. scan rate, iodide ion concentration, film thickness and acid conc...

in this work, modification of carbon paste electrode surface with poly (2, 5-dimethyl aniline) (p-2,5-dma) by using electrochemical polymerization was described. then, transition metal ions of ni(ii) were incorporated into the polymer film by two ways. at first way, the polymeric modified electrode was immersed in 0.2 m niso4 solutions and the second way was carried out by electrodeposition of ...

A novel polycalconcarboxylic acid (CCA) modified glassy carbon electrode (GCE) was fabricated by electropolymerization and then successfully used to simultaneously determine ascorbic acid (AA), norepinephrine (NE) and uric acid (UA). The characterization of electrochemically synthesized Poly-CCA film was investigated by atomic force microscopy (AFM), electrochemical impedance spectroscopy (EIS)...