In the title picrate salt of a dihalogenated aniline derivative, C(6)H(6)ClF(+)·C(6)H(2)N(3)O(7) (-), the intra-cyclic C-C-C angles in the picrate anion cover a broad range [111.95 (12)-125.38 (13)°], while those in the aromatic cation span a much narrower range [118.25 (14)-122.33 (13)°]. In the crystal, classical N-H⋯O hydrogen bonds, as well as C-H⋯O contacts, connect the ions into layers pa...

IN THE CATION OF THE TITLE SALT (SYSTEMATIC NAME: 5-{5-chloro-3-[4-(methyl-sulfon-yl)phen-yl]-2-pyrid-yl}-2-methyl-pyridinium 2,4,6-trinitro-phenolate), C(18)H(16)ClN(2)O(2)S(+)·C(6)H(2)N(3)O(7) (-), the mean planes of the two pyridine rings in the bipyridine unit are twisted by 33.9 (2)° with respect to each other. The dihedral angles between the mean planes of the sulfonyl-benzene ring and th...

In the title molecular salt {systematic name: N,N-dimethyl-2-[(2-methyl-phen-yl)(phen-yl)meth-oxy]ethanaminium 2,4,6-tri-nitro-phenolate}, C(18)H(24)NO(+)·C(6)H(2)N(3)O(7) (-), the phenyl rings of the orphenadrinum cation are disordered [occupancies = 0.662 (4) and 0.338 (4)]. The N atom in the orphenadrinum cation is protonated. The picrate anion inter-acts with the protonated N atom through a...

The title compound, H(3)O(+)·C(6)H(2)N(3)O(7) (-), consists of one picrate anion and one oxonium cation. The oxonium cation is located on a crystallographic twofold axis and both its H atoms are disordered, each over two symmetry-equivalent positions with occupancy ratios of 0.75. The picrate anions are also located on twofold axes bis-ecting the phenolate and p-nitro groups. π-π inter-actions ...

In the title salt {systematic name: 4-diphenyl-methyl-1-[(E)-3-phenyl-prop-2-en-1-yl]piperazin-1-ium 2,4,6-trinitro-pheno-late), C(26)H(29)N(2) (+)·C(6)H(2)N(3)O(7) (-), the cinnarizinium cation is protonated at the piperazine N atom connected to the styrenylmethyl group; the piperazine ring adopts a distorted chair conformaiton. In the crystal, bifurcated N-H⋯(O,O) hydrogen bonds link the comp...

In the title salt {systematic name: [2-hy-droxy-3-(3-meth-oxy-phen-yl)cyclo-hexyl-meth-yl]dimethyl-aza-nium 2,4,6-trinitro-phenol-ate}, C(16)H(26)NO(2) (+)·C(6)H(2)N(3)O(7) (-), the cation is protonated at the N atom. The cyclo-hexane ring adopts a chair conformation with the hy-droxy substituent in an axial position. In the crystal, O-H⋯O and N-H⋯O hydrogen bonds link the cations and anions in...