The framework of non-equilibrium thermodynamics (NET) is used to derive heat and mass transport equations for pervaporation of a binary mixture in a membrane. In this study, the assumption of equilibrium of the sorbed phase in the membrane and the adjacent phases at the feed and permeate sides of the membrane is abandoned, defining the interface properties using local equilibrium. The transport...

Although several separation technologies are technically capable of removing volatile products from fermentation broths, distillation remains the dominant technology. In this presentation, the status of an emerging membrane-based technology called pervaporation for the recovery of biofuels such as ethanol is reviewed and options for integrating pervaporation units with fermentors will be discus...

Increasing the hydrophobicity of membrane was believed as an effective approach to enhance the performance of organophilic pervaporation (PV) membrane. In this work, the superhydrophobic alkyl group modificated metal organic framework (MOF) of RHO-[Zn(eim)2] (MAF-6) was incorporated into polydimethylsiloxane (PDMS) polymer to fabricate mixed matrix membranes (MMMs). The morphologies, physical a...

The effects of operating parameters such as feed temperature and permeate-side pressure on the performance of a commercial PVA membrane in the dehydration of toluene by a pervaporation (PV) membrane system is studied in the present work. The results obtained indicate that increasing temperature in the range of 40 to 70 °C and reducing permeate pressure in the range of 1 to 10 mmHg increase memb...

A graphene oxide (GO) membrane is supported on a ceramic hollow fiber prepared by a vacuum suction method. This GO membrane exhibited excellent water permeation for dimethyl carbonate/water mixtures through a pervaporation process. At 25 °C and 2.6 wt % feed water content, the permeate water content reached 95.2 wt% with a high permeation flux (1702 g m(-2) h(-1)).

Pervaporation has a high potential for separating miscible solutions, particularly azeotropic mixtures. However, mass transfer limitations have long been common concern in pervaporation device design. Therefore, this work, we design static mixer-based using water–ethanol separation as model system and further develop computational fluid dynamics tools to investigate systematically all the influ...

This paper focuses on the effects of the addition of an ionic liquid, 1-Allyl-3-butylimidazilium bis(trifluoromethane sulfonyl)imide ([ABIM]TFSI), which has a high affinity for benzene, into the poly(vinyl chloride) (PVC) membrane on the pervaporation characteristics of the removal of benzene from aqueous solutions of dilute benzene. When aqueous solutions of 100～500 ppm benzene were permeated ...

BACKGROUND Butanol is regarded as an advanced biofuel that can be derived from renewable biomass. However, the main challenge for microbial butanol production is low butanol titer, yield and productivity, leading to intensive energy consumption in product recovery. Various alternative separation technologies such as extraction, adsorption and gas stripping, etc., could be integrated with aceton...

Membrane-based pervaporation (PV) has attracted much attention in the dehydration of organic solvents. Permeate pressure and feed flow rate are two important parameters, which affect membrane performance in pervaporation. The effects of these two parameters on the performance of a commercial poly (vinyl alcohol) membrane in the dehydration of benzene have been investigated in this work. The exp...