To fabricate a defect free and high performance mixed matrix membrane (MMM), one approach is the functionalization of inorganic nanofillers (as dispersed phase) in the organic polymer matrix (as continuous phase) to modify the interactions between two phases.  For this purpose,, raw multi-walled carbon nanotubes (rMWCNTs) were purified by acid mixture (HNO3/H2SO<sub...

Electrospinning of nanofibers with cyclodextrin (CD) is attractive because the produced fibers can potentially increase the efficiency of nanofibrous membranes by facilitating the complex formation with organic compounds and high surface area of the nanofibers. In this work, polyacrylonitrile (PAN) nanofibers functionalized with β– cyclodextrin (βCD) during an electrospinning process were used ...

1387-1811/$ see front matter 2012 Elsevier Inc. A http://dx.doi.org/10.1016/j.micromeso.2012.03.052 ⇑ Corresponding authors. E-mail addresses: [email protected] (C.W. Jo ch.edu (S. Nair). The effect of typical membrane processing conditions on the structure, interfacial morphology, and gas separation performance of MOF/polymer nanocomposite membranes is investigated. In particular, the ZIF...

Trimethylene glycol dimethyl ether (triglyme), a Polyethylene glycol (PEG)-like hydrophilic polymer, was deposited by plasma polymerization to reduce RO membrane’s organic fouling tendency. This method has the great advantage of achieving modification in one single step. A series of plasma deposition experiments were undertaken. The successful coating of the polymer was confirmed by X-ray photo...

New TiO2-based hybrid materials composed of an organic polymer, cellulose acetate butyrate and copolymer of acrylonitrile acrylamide (AN + AA) were prepared. The effectiveness of immobilization of microbial strain Arthrobacter oxydans 1388 on the newly synthesized hybrid membranes was investigated by biochemical methods. The obtained results revealed that the matrix more suitable for biofilm fo...

Nanoporous membranes with superior separation performance have become more crucial with increasing concerns in functional nanomaterials. Here novel ultrahigh permeable nanoporous membranes have been fabricated on macroporous supports by self-assembly of anionic polymer on copper hydroxide nanostrand templates in organic solution. This facile approach has a great potential for the fabrication of...

In the present study, the permeabilities of CO2 and CH4 in terms of ideal and actual CO2/CH4 selectivity were investigated through the synthesized membranes of poly (ether-block-amide) (Pebax 1657) accompanied with poly (ethylene glycol) (PEG 400) and NH2-MIL125 nanoparticles. NH2-MIL125 nanofillers were added to the blend of PEG...

Covalent organic frameworks (COFs) show advantageous characteristics, such as an ordered pore structure and a large surface area for gas storage separation, energy storage, catalysis, molecular separation. However, COFs usually exist difficult-to-process powders, preparing continuous, robust, flexible, foldable, rollable COF membranes is still challenge. Herein, with fiber morphology the first ...