A new bulky pyrene-derived elongated cross-shaped organic scaffold was successfully incorporated into a highly porous, noninterpenetrated square-grid copper(II)-organic framework material with the unprecedentedly huge dimensions of 25.5 x 25.5 A(2), while the layer-to-layer NH...N interaction leads to a unique hydrogen-bonded 6(4).8(2)-nbo net.

Very thin (2.3-5.5 nm) self-assembled organic dielectric multilayers have been integrated into organic thin-film transistor structures to achieve sub-1-V operating characteristics. These new dielectrics are fabricated by means of layer-by-layer solution phase deposition of molecular silicon precursors, resulting in smooth, nanostructurally well defined, strongly adherent, thermally stable, virt...

Organic photovoltaic cell (OPV) has emerged as a new competitor to inorganic material-based solar cells, due to its potential application in large area, printable, and flexible solar panels. In particular, OPV cells with bulk heterojunction architecture (BHJ), in which the photoactive layer consists of a bicontinuous blend of an electron donor and an electron acceptor, has allowed power convers...

The roles of substrate availability and quality in determining temperature sensitivity (Q10) of soil carbon (C) decomposition are still unclear, which limits our ability to predict how soil C storage and cycling would respond to climate change. Here we determined Q10 in surface organic layer and subsurface mineral soil along an elevation gradient in a temperate forest ecosystem. Q10 was calcula...

Fundamental processes induced in a thick organic system composed of long, well-organized linear molecules by an impact of 5–20 keV C60 are investigated. The organic system is represented by Langmuir– Blodgett multilayers formed from bariated molecules of arachidic acid. The thickness of the system varies between 2 and 16 nm. Coarse-grained molecular dynamics computer simulations are applied to ...

A three-wavelength angular-scanning surface plasmon resonance based analysis has been utilized for characterizing optical properties of organic nanometer-thick layers with a wide range of thicknesses. The thickness and refractive index were determined for sample layers with thicknesses ranging from subnanometer to hundreds of nanometers. The analysis approach allows for simultaneous determinati...

[1] We investigated micromechanical properties and ultrastructure of the shells of the modern brachiopod species Lingula anatina, Discinisca laevis, and Discradisca stella with scanning electron microscopy (SEM, EDX), transmission electron microscopy (TEM) and Vickers microhardness indentation analyses. The shells are composed of two distinct layers, an outer primary layer and an inner secondar...