We describe the organic phase transfer of surfactant-stabilized rhodium nanoparticles previously synthesized in an aqueous solution of N,N-dimethyl-N-dodecyl-N-(2-hydroxyethyl)ammonium chloride (HEA12Cl); the addition of LiN(Tf)2 to the aqueous suspension of Rh-HEA12Cl transferred the hydrosol nanoparticles to an ionic liquid phase.

Oxygen reduction catalyzed by cobalt(II) (2,3,7,8,12,13,17,18-octaethylporphyrin) [Co(OEP)] at soft interfaces is studied by voltammetry and biphasic reactions. When Co(OEP) is present in a solution of 1,2-dichloroethane in contact with an aqueous acidic solution, oxygen is reduced if the interface is positively polarized (water phase versus organic phase). This reduction reaction is facilitate...

Novel organic-inorganic hybrid materials comprising nanoscaled layered silicates and native aluminium hydroxide phthalocyanine (Al(OH)Pc) allowed for the first time the exploitation of their unique photophysical properties in aqueous ambience. In particular, we were able to observe the efficient emission of Al(OH)Pc-nanoclay hybrids and generation of singlet oxygen in aqueous solution.

A microfluidic-based approach for the fabrication of organic contaminants absorbing core-shell particles is demonstrated. The hydrophobic porous core absorbs oil while the hydrophilic surface enables the particles to be well-dispersed in aqueous solutions. These particles can uptake oil from aqueous solution saturated with oil or via direct contact with oil blobs as depicted in the figure.

sawdust is now being investigated as an adsorbent to remove contaminants from aqueous solution. heavy metals can be decreased very effectively with the organic material. in this research, adsorption of pb (ii) onto modified beech sawdust in a batch system was investigated. sawdust was collected from timber mill of qom, iran, and modified with h2so4 and naoh. then, the effects of various paramet...

We report enhanced electrochemical detection of single water-in-oil emulsion droplets using the nano-impact method. To detect droplets, water molecules in were directly oxidized (i.e., splitting) without additional electroactive species when collided with ultramicroelectrode. The droplet cannot be electrolyzed an organic solvent because emulsifier does not require a hydrophobic electrolyte. enh...