The ABS2 sulphides (A=Cu, or Ag), B=As, Sb, Bi) are a naturally occurring group of minerals, typically found in polymetallic vein deposits. Behind chemically simple, the minerals have a complex structure and undergo several temperature/composition phase transitions. In this study, synchrotron radiation is used to collect Ag, As, Bi, Cu, Cd, Hg and Sb K-edge EXAFS data from a series of synthetic...