water-distilled essential oil of ferulago macrocarpa (umbelliferae) fruits was analyzed using gc-ms for the first time. forty-two components comprising 99.5% of the total oil were identified, of which bornyl acetate (40.8%), 2,3,6-trimethyl benzaldehyde (7.2%), δ-selinene (5.5%), 1,10-di-epi-cubenol (5.1%), germacrene d (3.5%), β-phellandrene (3.5%) and α-pinene (3.4%) were found to be the majo...

Olive oil and table olives are rich sources of biophenols, which provides a unique taste, aroma and potential health benefits. Specifically, green olive drupes are enriched with oleuropein, a bioactive biophenol secoiridoid. Olive oil contains hydrolytic derivatives such as hydroxytyrosol, oleacein and elenolate from oleuropein as well as tyrosol and oleocanthal from ligstroside. Biophenol seco...

Polyethylene glycols (PEGs) are products of condensed ethylene oxide and water that can have various derivatives and functions. Since many PEG types are hydrophilic, they are favorably used as penetration enhancers, especially in topical dermatological preparations. PEGs, together with their typically nonionic derivatives, are broadly utilized in cosmetic products as surfactants, emulsifiers, c...

Five branched oleochemicals were prepared from commercially available methyl oleate and common organic acids; and their lubricant properties were determined. These branched oleochemicals are characterized as 9(10)-hydroxy-10(9)-ester derivatives of methyl oleate. These derivatives show improved low temperature properties, over olefinic oleochemicals, as determined by pour point and cloud point ...

the rapid expansion in world production of palm oil over the last three decades has attracted the attention of the oils and fats industry. oil palm gives the highest yield of oil per unit of any crop. palm oil is the major oil produced, with annual world production in excess of 50 million tonnes. throughout the world, 90% of palm oil is used for edible purposes (e.g., margarine, deep fat frying...

Lipases are promising enzymes that catalyze the hydrolysis of triacylglycerol ester bonds at the oil/water interface. Apart from allowing biocatalyst reuse, immobilization can also affect enzyme structure consequently influencing its activity, selectivity, and stability. The lipase from Penicillium sp. section Gracilenta (CBMAI 1583) was successfully immobilized on supports bearing butyl, pheny...

The main aim of the present work was development of a quantitative structure-property relationship method using an artificial neural network (ANN) for predicting gas-to-olive oil partition coefficients of organic compounds. As a first step, a multiple linear regression (MLR) model was developed; the descriptors appearing in this model were considered as inputs for the ANN. These descriptors are...

The new crop oil from jojoba (Simmondsia chinensis) is a skin-softener similar to sperm whale oil. In an effort to find new uses of this oil, we have converted jojoba liquid wax into two new products in mild chemical processes. Tetrahydroxyjojoba wax (THJF) is a colorless, stable, low-melting solid and jojoba ferulate, an ultra violet (UV) absorbing species by esterification of the tetrahydroxy...

Essential oils from anise, hyssop, thyme, ginger, camomile and sandalwood were screened for their inhibitory effect against herpes simplex virus type 2 (HSV-2) in vitro on RC-37 cells using a plaque reduction assay. Genital herpes is a chronic, persistent infection spreading efficiently and silently as sexually transmitted disease through the population. Antiviral agents currently applied for t...

The CoI2(PPh3)2/Zn system effectively catalyzes the [2 + 2 + 2] ene-diyne cycloaddition of 1,6-heptadiynes with allenes in a highly regio- and chemoselective fashion to yield substituted benzene derivatives in good to excellent yields.