نتایج جستجو برای: of aromatics
تعداد نتایج: 21164521 فیلتر نتایج به سال:
We analyze the observations of near-surface peroxy acetyl nitrate (PAN) and its precursors in Beijing, China in August of 2007. The levels of PAN are remarkably high (up to 14 ppbv), surpassing those measured over other urban regions in recent years. Analyses employing a 1-D version of a chemical transport model (Regional chEmical and trAnsport Model, REAM) indicate that aromatic non-methane hy...
Reversible adlattice assembly for alkoxy-decorated aromatics is controllable by short electrical pulses.
The effectiveness of an extractive distillation process relies on the choice of the extractive solvent. The conventional methodology to select solvents is based on Group Contribution Methods. Ionic liquids have shown several advantages over conventional solvents used in extractive distillation and liquid-liquid extraction processes. However, there is no existing methodology to select ILs as sol...
A Lewis acid-catalyzed nucleophilic addition of electron rich aromatics with 3-hydroxy-2-oxindoles 5 was developed. The reaction is believed to proceed through the 2H-indol-2-one ring system 9, which eventually reacts with various electron-rich aromatics to afford a variety of 2-oxindoles with an all-carbon quaternary center at the pseudobenzylic position (4, 8, 13, and 16) in high yields. The ...
Aromatic compounds are widely distributed in nature. They are found as lignin components, aromatic amino acids, and xenobiotic compounds, among others. Microorganisms, mostly bacteria, degrade an impressive variety of such chemical structures. Various aerobic aromatic catabolic pathways have been reported in bacteria, which typically consist of activation of the aromatic ring through oxygenases...
The scope and limitations of direct arylation of fluorinated aromatics with aryl sulfonates was examined. Pd(OAc)(2), in the presence of MePhos and KOAc in THF, efficiently catalyzed the direct arylation of fluoro aromatics with aryl triflates under ambient conditions. Sterically hindered triflates and heteroaryl triflates gave good to excellent yields of the cross coupled products using a modi...
Hydrocarbons are organic compounds consisting of C-C and C-H bonds. Carbon has a valence of four and thus requires four electrons or bonds to complete its octet in the neutral state. Hydrogen has a valence of one and thus requires a single electron or bond to complete its "duet" in the neutral state. Thus in hydrocarbons carbon can form neutral bonding arrangements by forming single bonds with ...
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