This work reports a sensitive amperometric biosensor for organophosphate pesticides (OPs) fabricated by modifying a glassy carbon electrode with acetylcholinesterase (AChE) immobilized on ionic liquid-functionalized graphene (IL-G). The functionalized graphene sheets had good dispersibility and long-term stability in various solvents. The as-prepared biosensor showed high affinity to acetylthio...

In this article, we study on the effect of different congregated granularities of microencapsulated n-octadecane on polyurethane foamed system, and the making of the polyurethane foams with high contents of microencapsulated n-octadecane. The results show that, when relative low granularities of microencapsulated phase change materials (MicroPCMs) are used as additives, the remnant water and fo...

We report on the direct and facile method for noble metal/graphene nano-composites from graphite without reducing agents. In this system, the irradiant white-light instead of the chemical reducing agent exerts the influence on the synthesis of noble metal nanoparticles on graphene. Noble metal salts adsorbed on graphene flakes which were functionalized with ionic surfactants were reduced by irr...

A convenient sonochemical method is described for the preparation of polystyrene functionalized graphenes starting from graphite flakes and a reactive monomer, styrene. Ultrasonic irradiation of graphite in styrene results in the mechanochemical exfoliation of graphite flakes to single-layer and few-layer graphene sheets combined with functionalization of the graphene with polystyrene chains. T...

We report the synthesized and preparation of graphene oxide (GO) nanocomposite functionalized with polyvinyl alcohol (PVA) with different concentration of graphene oxide 0, 1, 1.5, 2, 2.5, 3, 3.5 and 4% weight. This synthesized confirmed by FT-IR. The electrical conductivity of the all nanocomposite was measured at 25°C for all samples and the resulted showed electrical conductivity ...

We study the mechanism of surface adsorption of organic dyes on graphene, and successive exfoliation in water of these dye-functionalized graphene sheets. A systematic, comparative study is performed on pyrenes functionalized with an increasing number of sulfonic groups. By combining experimental and modeling investigations, we find an unambiguous correlation between the graphene-dye interactio...

The lithium-air battery is one of the most promising technologies among various electrochemical energy storage systems. We demonstrate that a novel air electrode consisting of an unusual hierarchical arrangement of functionalized graphene sheets (with no catalyst) delivers an exceptionally high capacity of 15000 mAh/g in lithium-O(2) batteries which is the highest value ever reported in this fi...

In order to engineer a band gap into graphene, covalent bond-forming reactions can be used to change the hybridization of the graphitic atoms from sp(2) to sp(3), thereby modifying the conjugation length of the delocalized carbon lattice; similar side-wall chemistry has been shown to introduce a band gap into metallic single-walled carbon nanotubes. Here we demonstrate that the application of s...

In this study, we put forward a non-covalent π-π interaction between graphene nanoparticles (G) and pyrene-based molecule (py) to give the functionalized (G-py). The proposed modification has proven be winning solution aimed at safeguarding graphene's striking electronic properties, while favoring more effective nanofiller dispersion due decrease in viscosity with consequent improvement of rheo...

It has recently published that graphene oxide (GO) obtained from graphite by Hummers’ oxidation is composed by nanoplatelets, named as GOP and oxidative debris (OD). OD seems to be composed by highly oxidative aromatic molecules coming from rupture of the sheets and they are adsorbed on the top of the nanoplatelets. The existence of OD modifies the physical and chemical properties of the materi...