Metallocluster-containing enzymes catalyze some of the most basic redox transformations in the biosphere. The reactions catalyzed by these enzymes typically involve small molecules such as N2, CO, and H2 that are used to generate both chemical building blocks and energy for metabolic purposes. During the past decade, structures have been established for the iron-sulfur-based metalloclusters pre...

Nano oxides of Manganese Nickel and Cobalt Nickel were synthesized by chemical coprecipitation method from the reaction of respective metal sulfides of manganese, nickel, cobalt and sodium carbonate using ethylene diamene tetra acetic acid as an effective capping agent. The carbonate precursors were heated at different temperatures so as to form their oxides. Through the X-ray line broadening t...

The synthesis of nickel oxide nanoparticles in film form using dead biomass of the filamentous fungus Aspergillus aculeatus as reducing agent represents an environmentally friendly nanotechnological innovation. The optimal conditions and the capacity of dead biomass to uptake and produce nanoparticles were evaluated by analyzing the biosorption of nickel by the fungus. The structural characteri...

in internal combustion engines, only about a third of the total fuel input energy is converted into useful work. if the energy rejected into the cooling system and the exhaust gases could be recovered instead and put into useful work, fuel economy would have been substantially improved. the main aim of this research paper was to evaluate the effects of the hybrid nano-catalyst containing cerium...

In the present study, nanocrystalline Ni50Al50-xMox (X = 0, 0.5, 1, 2.5, 5) intermetallic compound was produced through mechanical alloying of nickel, aluminum, and molybdenum powders. AlNi compounds with good and attractive properties such as high melting point, high strength to weight ratio and high corrosion resistance especially at high temperatures have attracted the attention of many rese...

www.sciencemag.org SCIENCE VOL 327 1 JANUARY 2010 7 COVER Crystal structure of a molybdenum oxide nanowheel, 2.6 nanometers in diameter, around a smaller molybdenum oxide cluster. Miras et al. (page 72; related Perspective page 38) used a controlled-flow reactor to show that the central core serves as a transient template for the self-assembly of the nanowheel and is ultimately ejected to yield...

In this research, the nickel oxide was dissolved in cryolite at temperatures of 880, 940 and 1000°C. In order to reduce the nickel oxide, aluminum was added to the salt. Simultaneously the nickel oxide was reduced and Al3Ni2 intermetallic compound was formed. In the duration intervals of 2.5-40 minutes samples of the salt and metallic phases were taken. The variation of the nickel content in me...

Encapsulation of molybdenum oxide MoO3 into ordered mesoporous silica materials is demonstrated using different synthetic routes. Either supramolecular polyoxometalates of the “Müller type” or Na2MoO4 were used as precursors. Molybdenum oxide (MoO3)-silica hybrid materials were characterized using nitrogen-sorption experiments, transmission electron microscopy, small-angle X-ray scattering, and...

The identification, fine-tuning, and process optimization of appropriate hole transporting layers (HTLs) for organic solar cells is indispensable for the production of efficient and sustainable functional devices. In this study, the optimization of a solution-processed molybdenum oxide (MoOx) layer fabricated from a combustion precursor is carried out via the introduction of zirconium and tin a...

Manganese-nickel (Mn-Ni) oxide films were electrodeposited on a graphite sheet in a bath consisting of manganese acetate and nickel chloride, and the structural, morphological, and electrochemical properties of these films were investigated. The electrodeposited Mn-Ni oxide films had porous structures covered with nanofibers. The X-ray diffractometer pattern revealed the presence of separate ma...