zeolite fau type-y is one of the most studied framework of all zeolites, and has been used as catalysts for number of reactions in the refinery and petrochemical industry. in this research, nanocrystalline zeolite y was synthesized by hydrothermal method. the crystal size of zeolite y is influenced by temperature, aging time, alkalinity, and water content. the synthesized zeolite nay is identif...

The one-pot Diels-Alder cycloaddition (DAC)/dehydration (D) tandem reaction between 2,5-dimethylfuran and ethylene is a potent pathway toward biomass-derived p-xylene. In this work, we present a cheap and active low-silica potassium-exchanged faujasite (KY, Si/Al = 2.6) catalyst. Catalyst optimization was guided by a computational study of the DAC/D reaction mechanism over different alkali-exch...

Carbonylation gets a phase lift: The usual liquid-phase, high-pressure processes for carbonylating formaldehydes are avoided in a novel vapor-phase reaction. Using an acid zeolite (Faujasite) at near-atmospheric pressure dimethoxymethane (DMM; the dimethyl acetal of formaldehyde; see scheme) is carbonylated to produce methyl methoxyacetate (MMAc). This approach provides a new route to ethylene ...

This work investigates the oxidation of nitrobenzene (NB) by ozone in the presence of faujasite zeolite. Experiments were carried out in a gas-liquid-solid reactor were ozone transfer and NB oxidation took place at the same time. Three configurations of the reactor were compared: empty, filled with inert glass beads and filled with faujasite pellets. First, ozone transfer coefficient (k(L)a) an...

in this work, zeolite nay was prepared by hydrothermal method. then, silver ions were replaced in the zeolite nay with silver nitrate (agno3) solution via using ion exchange (ie) method. the manganese dioxide (mno2) nanoparticles (9.3 and 15.8 wt %) for guest were deposited in the zeolite agy(host) structure with mn(no3)2 aqueous and kmno4 solutions by confined space synthesis (css) method. syn...

NaY zeolite, an ordered, large pore molecular sieve pertaining to the FAU zeolite structural group, was studied as a novel matrix for efficient preparation of supported isothiazolinone-based biocide, and results were compared those corresponding mesoporous silicas. To analyze possibility reducing biocide ecotoxicity by encapsulation, commercial used latex preservation (CMIT/MIT) incorporated in...

Reaction mechanisms for the catalytic hydrogenation of CO2 by faujasite-supported Ir4 clusters were studied by periodic DFT calculations. The reaction can proceed through two alternative paths. The thermodynamically favoured path results in the reduction of CO2 to CO, whereas the other, kinetically preferred channel involves CO2 hydrogenation to formic acid under water-free conditions. Both pat...

Introduction i 1 1. The Principles of Simulated Moving Bed Chromatography 3 1.1 Continuous counter current adsorption systems 3 1.2 The simulated moving bed process 4 1.2.1 The four-section SMB cascade 5 2. Modeling of SMB Column 2.1 Equivalent counter-current model 8 8 3. Characteristics of Adsorbents and Modeling Results 11 3.1 Ca2+ exchanged ion exchange Non-polar dealuminated Faujasite zeol...

Recently, hybrid materials using poly ethylene glycol and porous nanocrystals have been developed for drug release. In this study, a series of poly ethylene glycol (PEG)/NaY zeolite and PEG/MCM-41 nanocomposites get synthesized. These materials are characterized using FT-IR spectroscopy, XRD, TGA and SEM. After loading the metronidazole onto these nanocomposites, the release of Metronidazole wa...

Dye-exchanged Y zeolite is shown to be an effective medium to control the stereoselectivity in the photooxygenation of chiral oxazolidinone-functionalized Z/E-1 enecarbamates. An enantioselectivity (ee) as high as 80% was observed in the methyldesoxybenzoin (MDB) product, obtained in the methylene-blue-exchanged NaY zeolite at room temperature. The efficacy of the asymmetric induction in the MD...