A modified electrode was prepared by modification of the carbon paste electrode (CPE) with graphene nano-sheets. The fabricated modified electrode exhibited an electrocatalytic activity toward gallic acid (GA) oxidation because of good conductivity, low electron transfer resistance and catalytic effect. The graphene modified CPE had a lower overvoltage and enhanced electrical current respect to...

the voltammetric performance of edge-plane pyrolytic graphite (epg) electrode via adsorptive stripping voltammetry was investigated for study of the electrochemical behavior of omeprazole (omz) in aqueous solution. the results revealed that the oxidation of omz is an irreversible ph-dependent process that proceeds with the transfer of one electron and one proton in an adsorption-controlled mech...

in order to study the cu(ii) ion selective electrode, an optimized membrane was prepared by mixing of 30 mg of pvc powdered, 5 mg of considered ionophore, 60 mg of plasticizer and 5 mg of additive. the sensor showed a near nernstian response for cu(ii) ions over a concentration range from 1.0×0-6 –1.0×0-2 m with a slope of 28.90.5 mv per concentration decade with a working ph range of 3.5-6.3. ...

a sensor, based on multi-wall carbon nanotubes modified glassy carbon electrode (mwcnt/gce), was developed for determination of fenitrothion. determining the surface area of mwcnt/gce showed that this surface is three times more active than that of a glassy carbon electrode. the experimental parameters, such as the amount of mwcnts, ph of the fenitrothion solution, preconcentration potential an...

glassy carbon (gc) is the most commonly used carbon-based electrode in the analytical laboratory. because of the high background current and low electrode response, modification of this electrode can be done by various materials and techniques. an ionic liquid (il), 1-methyl-3-(3-trimethoxysilyl propyl) imidazoliumbis (trifluoromethylsulfonyl) imide, was covalently cross linked onto the gc surf...

a pvc-based membrane containing cerium phosphate was developed. unlike the cerium phosphate itself that acts as a cation exchanger, the membrane exhibited anion-exchange properties. therefore, the utility of this compound as a sensory element for detection of molybdate ions was pursued. the response of molybdate selective electrode based on this membrane was perfectly linear in the concentratio...

in this paper, using a one-dimensional simulation model, the reforming process of sour gas, i.e. ch4, co2, and h2s, to the various charged particles and syngas in a dielectric barrier discharge (dbd) reactor is studied. an electric field is applied across the reactor radius, and thus a non-thermal plasma discharge is formed within the reactor. based on the space-time coupled finite element meth...

the conditional formal potential, e°′of methyldopa has been studied by cyclic voltammetry at the surface of activated glassy carbon electrode (agce) as the working electrode in different ph phosphate buffered solutions. the experimental standard redox potential, e°′, of methyldopa is obtained to be 0.72 mv versus she (standard hydrogen electrode). e°′ values have also been calculated with the a...