Mixed holmium cobaltite-chromite HoCo0.5Cr0.5O3 with orthorhombic perovskite structure (structure type GdFeO3, space group Pbnm) was obtained by solid state reaction of corresponding oxides in air at 1373 K. Room- and high-temperature structural parameters were derived from high-resolution X-ray synchrotron powder diffraction data collected in situ in the temperature range of 300-1140 K. Analys...

The destruction of the ferromagnetism of alloyed SrRuO(3) can be caused by electron localization at the substitution sites. Among all the non-magnetic cations that enter the B site, Zr(4+) is the least disruptive to conductivity and ferromagnetism. This is because Zr(4+) does not cause any charge disorder, and its empty d electron states which are poorly matched in energy with the Ru t(2g)(4) s...

Perovskite oxides are attractive candidates as catalysts for the electrolysis of water in alkaline energy storage and conversion systems. However, the rational design of active catalysts has been hampered by the lack of understanding of the mechanism of water electrolysis on perovskite surfaces. Key parameters that have been overlooked include the role of oxygen vacancies, B-O bond covalency, a...

Iron cobaltite powders CoxFe3ÿxO4 (1rxr2.46) were synthesized with compositions in between the cobalt ferrite CoFe2O4 and Co2.46Fe0.54O4. The cationic distribution of pure spinel phases was determined by Mössbauer spectroscopy: as Co content increases in the spinel oxide, Co cations replace Fe cations in the octahedral sites and Co cations migrate from octahedral to tetrahedral sites. Saturatio...

Issues related to use of metallic interconnects in oxide thermoelectric generators (TEGs) need be addressed secure performance and durability. Metal suffer from high cost noble metals or chemical instability contact resistance non-noble metals, arising oxidation, evaporation, delamination the oxidising conditions ambient air at operating temperatures. This work introduces a stable highly conduc...

Recently, transition metal oxides, such as ruthenium oxide (RuO₂), manganese dioxide (MnO₂), nickel oxides (NiO) and cobalt oxide (Co₃O₄), have been widely investigated as electrode materials for pseudo-capacitors. In particular, these metal oxides with mesoporous structures have become very hot nanomaterials in the field of supercapacitors owing to their large specific surface areas and suitab...

The activity of electrocatalysts exhibits a strongly dependence on their electronic structures. Specifically, for perovskite oxides, Shao-Horn and co-workers have reported a correlation between the oxygen evolution reaction activity and the eg orbital occupation of transition-metal ions, which provides guidelines for the design of highly active catalysts. Here we demonstrate a facile method to ...

nowadays, the use of innovative nano-technology in the food industry quality control has significantly increased and it is widely employed in numerous fields such as diagnosis of microbial toxin of foods using nano-biosensors, increasing food shelf-life with the help of nano-clay and nano-silver packaging, as well as changing some of the unpleasant organoleptic properties such as taste, color, ...