نتایج جستجو برای: n heterocyclic plumbylenes

تعداد نتایج: 981945  

Journal: :European Journal of Inorganic Chemistry 2013

2005
Xiang-Ping Hu Hui-Lin Chen Zhuo Zheng

The presence of the additional heterocyclic nitrogen atoms in chiral P,N ligands has an important influence on the asymmetric catalysis, and a clear trend was observed in the present research that the enantioselectivity and reactivity were significantly increased by raising the number of heterocyclic nitrogen atoms in these P,N ligands. Through finely tuning the number of heterocyclic nitrogen ...

Journal: :Organic letters 2012
Nathan A Romero Benjamin M Klepser Carolyn E Anderson

A new Au(III)-catalyzed tandem amination-hydration reaction has been discovered, leading to the formation of α-(N-2-pyridonyl)ketones and heterocyclic analogues in good to excellent yields (14 examples, 48-90%). This reaction demonstrates the unusual use of a heterocyclic sp(2) nitrogen nucleophile in a gold-catalyzed 6-endo-dig cyclization. The tandem process allows rapid access to α-(N-2-pyri...

Journal: :Organic & biomolecular chemistry 2014
David E Stephens Gabriel Chavez Martin Valdes Monica Dovalina Hadi D Arman Oleg V Larionov

The scope and mechanistic implications of the direct transformation of heterocyclic N-oxides to 2-trifluoromethyl-, and related perfluoroalkyl- and perfluoroaryl-substituted N-heterocycles has been studied. The reaction is effected by perfluoroalkyl- and perfluorophenyltrimethylsilane in the presence of strong base. In situ displacement of the para-fluoro substituent in the pentafluorophenyl ri...

Journal: :Chemistry – A European Journal 2020

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