Incorporation of fluorene groups into the salicylidene moiety significantly enhances the luminescence of a number of multinuclear alkynylated Zn(II)-salophen complexes. Preparation of these complexes was achieved by a synthetic strategy with facile handling of the reactants, simple purification of the products, and one-pot reaction process. Two synthetic methods are used for the preparation of ...

The commitment process of a human megakaryoblastic cell line (MEG-01) induced with phorbol ester, TPA, was investigated with special reference to glycoprotein (GP) Ilb/ llla expression, multinuclear formation, and DNA replication. TPA (lo-’ mol/L) completely inhibited cellular division in MEG-01. but did not suppress de novo DNA synthesis. Two days’ culture with lo-’ mol/L TPA was sufficient fo...

The effects of a nitrogen mustard on both the morphology and several synthetic capacities of embryonic chick skeletal muscle cells in monolayer culture have been examined. Concentrations of nitrogen mustard which profoundly inhibit deoxyribonucleic acid synthesis specifically do not inhibit the development of multinuclearity in the contractile "ribbons" which form rapidly in culture. Nitrogen m...

We have exploited a property of chicken erythrocyte nuclei to analyze the regulation of DNA replication in a cell-free system from Xenopus eggs. Many individual demembranated nuclei added to the extract often became enclosed within a common nuclear membrane. Nuclei within such a "multinuclear aggregate" lacked individual membranes but shared the perimeter membrane of the aggregate. Individual n...

Abstract The development of efficient electrocatalysts based on non-noble metals for oxygen evolution reaction (OER) remains an important and challenging task. Multinuclear transition-metal clusters with high structural stability are promising OER catalysts but their catalytic role is poorly understood. Here we report the crystallographic observation activity over robust {Ni 12 }-clusters immob...