Reaction of the C(3)-symmetric triazine bridged tris(benzene-o-dithiol) ligand H(6)-1 with Ti(4+) leads to the unexpected formation of the dinuclear complex (Me(3)PhN)(4)[Ti(2)(1)(2)] while other C(3)-symmetric ligands are reported to form either mono- or tetranuclear complexes.

electrochemical behavior of the new mono and dinuclear co (iii)  complexes of  the types trans-[pyco((do)(doh)pn )(l)]pf6   and [{py co((do)(doh)pn)}2 (μ-dicyd)] (pf6)2   have been studied in acetonitrile solution.  all the  mono nuclear complexes  show two quasi- reversible reduction couples associate  to co(iii/ii)and  co(ii/i). each of these redox couples split to two  one electron  waves in...

let be a set and let be the set of subsets of . the pair in which is a collection of elements of (blocks) is called a design if every element of appears in , times. is called a symmetric design if . in a symmetric design, each element of appears times in blocks of . a mapping between two designs and is an isomorphism if is a one-to-one correspondence and . every isomorphism of a design, , to it...

The hybrid visible light communication/radio frequency (VLC/RF) transmission system could offer consistent coverage and high throughput, which are inherited from the VLC RF link components separately. However, almost all current VLC/RF schemes limited in scenarios adopting emitting diodes (LED) sources with basic Lambertian optical beams, fail to investigate using distinct non-Lambertian beams....

Five methods are introduced for design of castellated I beams encased in concrete. One of the methods, plastic analysis, is thoroughly explained and the relevant equations are developed. Eight castellated I beams encased in concrete are made and tested. The theoretical design methods are all compared with the test results and the safety factor for each method is calculated. The results show tha...

Five methods are introduced for design of castellated I beams encased in concrete. One of the methods, plastic analysis, is thoroughly explained and the relevant equations are developed. Eight castellated I beams encased in concrete are made and tested. The theoretical design methods are all compared with the test results and the safety factor for each method is calculated. The results show tha...

In the first part; the syntheses of mono-; di-; and tetra-glycosylated phthalonitriles is described; which are the most used starting materials for the preparation of the corresponding glycosylated metal (mostly zinc) phthalocyanines. In the second section; the preparation of symmetric and unsymmetric mono-; tetra-; and octa- glycosylated zinc phthalocyanines are reviewed; in which the sugar is...

Mono and bis hexamethylenetetramine iron(III) chloride, Fe(N C ,H ) CI (I) and Fe(N C ,H ) Cl (II) were synthesized by the reaction of iron(III) chloride and hexamethylenetetramine (HMTA) in chloroform. Chemical analysis and spectral results show the coordination of HMTA to the iron(III). Electronic transition spectra of compound I and I1 were also studied in coordinating and noncoordinatin...

Considering a generic double-ring collider, we discuss the matching from an antisymmetric optics in the arcs to a symmetric optics in the interaction region (IR) by means of an antisymmetric matching section. As an example, we present an application to the LHC, for which a symmetric IR with extremely flat beams is under study.