In the solid-state synthesis of impurity-doped CaGa(2)S(4), calcium tetra-thio-digallate(III), a novel phosphor material (denominated as the X-phase), with monoclinic symmetry in the space group P2(1)/a, has been discovered. Its emission intensity is higher than that of the known ortho-rhom-bic polymorph of CaGa(2)S(4) crystallizing in the space group Fddd. The asymmetric unit of the monoclinic...

We present a green route for the colloidal synthesis of undoped and silver (Ag) doped cadmium sulfide (CdS) quantum dots (QDs). have used olive oil as reaction medium, which acted source oleic acid (OA) ligand in CdS QDs. With increase OA concentration, dispersibility QDs improved. The water-dispersible were prepared via exchanging OA’s associated with 3-mercaptopropionic (MPA). MPA-capped show...

mn doped zno nanocomposite thin film coated on glass by a simple spin-coating method was used to degrade an azo textile dye from aqueous environment. mn doped zno nanocomposite thin film was characterized by means of x-ray diffraction (xrd) and scanning electron microscopy (sem). the photo-reduction activity of photocatalyst was evaluated using an azo textile dye as organic contaminant irradiat...

Metallothioneins are small cysteine-rich proteins coordinating various transition metal ions preferably with the electron configuration d(10). They are ubiquitously present in all phyla, and next to phytochelatins they represent a successful molecular concept for high-capacity metal ion binding. Recent studies showed the incorporation of sulfide ions into the metal-thiolate cluster of metalloth...

ZnO nanorods (NRs) arrays doped with a large concentration of Mn synthesized by aqueous chemical growth and were characterized by SEM, photoluminescence, Raman scattering, magnetic force microscopy (MFM). By comparison of spectra taken on pure and Mn-doped ZnO NRs, a few new Raman impurity-related phonon modes, resulting from the presence of Mn in the investigated samples. We also present a vib...

Using MnSO4 ̈H2O as manganese source and urea as nitrogen source, Mn/N co-doped TiO2 loaded on wood-based activated carbon fiber (Mn/Ti-N-WACF) was prepared by sol–gel method. Mn/Ti-N-WACF with different Mn doping contents was characterized by scanning electron microscopy, X-ray diffraction (XRD) and X-ray photoelectron spectroscopies (XPS), and ultraviolet-visible spectrophotometer. Results sho...

Mn-doped TiO₂ loaded on wood-based activated carbon fiber (Mn/TiO₂-WACF) was prepared by sol-gel and impregnation method using MnSO₄·H₂O as manganese source. The structure of Mn/TiO₂-WACF was characterized by SEM, XRD, FTIR, N₂ adsorption and UV-Vis, and its photocatalytic activity for methylene blue degradation was investigated. Results show that Mn-doped TiO₂ were loaded on the surface of woo...

Nanohelices of cadmium sulfide (CdS) have been made by the mineralization of supramolecular organic ribbons. A schematic representation of how coiled CdS helices (yellow) can be templated from a twisted ribbon (blue) by growth along one face of the ribbon is shown top right.

Plasmid-determined resistance to cadmium has only been found with plasmids from Staphylococcus aureus. Resistance to cadmium was associated with a lower accumulation of Cd(2+) ions by the plasmid-bearing resistant cells. Cadmium accumulation by susceptible cells was energy dependent and had those characteristics usually associated with a transmembrane active transport system. There was a specif...