The temperature dependence of the first three interlayer distances of the Ag(111) surface was studied by low-energy electron diffraction (LEED) over the temperature range 128K to 723 K. The first three interlayer spacings and the effective Debye temperatures were extracted from the LEED analysis. At the lowest temperature, the first two interlayer spacings are slightly (0.5 %) contracted. All t...

Polymer-layered silicate nanocomposites belong to a new class of hybrid materials consisting of organic-synthetic polymer matrix and inorganic filler-layered structure clay minerals. The paper presents the results of FTIR, NMR, and SAXS studies of poly(ε-caprolactone)/sodium montmorillonite nanocomposites. We observed a correlation between the concentration of poly(ε-caprolactone) in nanocompos...

Weak interlayer interactions in van der Waals crystals facilitate their mechanical exfoliation to monolayer and few-layer two-dimensional materials, which often exhibit striking physical phenomena absent in their bulk form. Here we utilize mechanical exfoliation to produce a two-dimensional form of a mineral franckeite and show that the phase segregation of chemical species into discrete layers...

-The electrostatic lattice energy of polar phyllosilicates can be calculated when a correction term E .... equal to -2r is taken into account, where/~ is the dipole moment of a slice d(001) and V is the molecular volume. The interlayer bonding energy can be obtained by Giese's method, if the energy of separation of the layers over a distance A is plotted againts 1/[d(001) + A]. Thus, for a pola...

Van der Waals bound heterostructures constructed with two-dimensional materials, such as graphene, boron nitride and transition metal dichalcogenides, have sparked wide interest in device physics and technologies at the two-dimensional limit. One highly coveted heterostructure is that of differing monolayer transition metal dichalcogenides with type-II band alignment, with bound electrons and h...

Success in the exfoliation of the stacked T-functionalized titanium carbide MXenes Tin+1CnT2 (T = OH, O, and F) would potentially extend their application scope, which requires an understanding of the nature of interlayer coupling. Here, we report for the first time the intrinsic interlayer coupling in pristine MXenes on the basis of first-principles calculations by taking long-range interactio...

An understanding of the interaction mechanisms between exchangeable cations and layered silicates is of interest from both a basic and an applied point of view. Among 2:1 phyllosilicates, a new family of swelling high-charge synthetic micas has been shown to be potentially useful as decontaminant. However, the location of the interlayer cations, their acidity and the water structure in the inte...

Graphite and hexagonal boron nitride (h-BN) are two prominent members of the family of layered materials possessing a hexagonal lattice structure. While graphite has nonpolar homonuclear C-C intralayer bonds, h-BN presents highly polar B-N bonds resulting in different optimal stacking modes of the two materials in the bulk form. Furthermore, the static polarizabilities of the constituent atoms ...

A model with interlayer pairing is proposed to explain the sinusoidal modulation of the resonant neutron scattering in high temperature superconductors. It is found that the interlayer pairing has s-wave symmetry in the CuO2 plane and has comparable magnitude with the d-wave intralayer pairing. It is also found that the interlayer pairing mainly affects momentum close to the hot spots on the Fe...

We investigate the relationship of the spontaneously interlayer coherent ‘‘111’’ state of quantum Hall bilayers at total filling factor n51 to ‘‘mutual’’ composite fermions, in which vortices in one layer are bound to electrons in the other. Pairing of the mutual composite fermions leads to the low-energy properties of the 111 state, as we explicitly demonstrate using field-theoretic techniques...