Hydrogen was produced by steam reforming of dimethyl ether (DME) using a physical mixture of commercial HZSM-5 zeolite (for DME hydrolyzing) and Cu/ZnO/Al2O3 (for methanol steam reforming) as a catalyst in a fixed bed reactor. The experiments were performed at atmospheric pressure and in a temperature range from 270 to 310 °C. The effects of feed temperature and gas hourly space velocity (GHSV)...

Introduction Hydrogen as a fuel has recently been an important issue due to developments in fuel cell technology. Hydrogen production from sustainable sources, e.g. biomass, is gaining attention for a CO2 neutral energy supply. Recent developments in flash pyrolysis technologies make it possible to convert lignocellulosic biomass efficiently to a bio-oil, which is easier for handling and transp...

Many attempts have been made to improve heat transfer for thermally integrated microchannel reforming reactors. However, the mechanisms effects of design factors on characteristics are still not fully understood. This study relates a thermochemical process producing hydrogen by catalytic endothermic reaction methanol with steam in reactor. Computational fluid dynamics simulations conducted bett...

Introduction Reforming (i.e., partial oxidation, steam reforming, or autothermal reforming (ATR)) of infrastructure fuels, such as natural gas, liquefied petroleum gas, gasoline, or diesel, is one approach being investigated for distributed H2 production for use with fuel cell systems being developed for automotive and stationary applications. One area of interest is reforming gasoline either o...

Environmental considerations will probably change automobile fuels from gasoline and gas-oil to hydrogen (as fuel cell) in the future. Problems of fossil fuels include producing gaseous pollutants, such as NOx, CO, and even SO2 (from incomplete-hydrotreated fuels), which need catalytic converters and greenhouse gas emission (such as CO2, CH4, N2O) from the exhaust with a drastic effect on globa...

This work was funded by the Hydrogen Program Office of the U.S. Department of Energy under Grant No. DE-FG01-99EE35099 and represents the second task of three to be completed under this contract. The first task presented a broad overview of the costs for creating infrastructures to supply direct hydrogen, methanol, and gasoline to support fuel cell vehicles (FCV’s). A conclusion of the report r...

A micro-channel heat exchanger reactor with different micro-baffle shapes has been studied numerically. Governing equations were solved base on the finite volume method with FLUENT software. In upper section, oxidation reaction of methanol was occurred and in lower section, steam reforming of methanol was done. Two sections were separated with solid part which played as heat exchanger and trans...

This paper presents a numerical and experimental study on the performance of a methanol steam reformer integrated with a hydrogen/air combustion reactor for hydrogen production. A CFD-based 3D model with mass and momentum transport and temperature characteristics is established. The simulation results show that better performance is achieved in the cross-U type reactor compared to either a tubu...

Methanol is a versatile chemical feedstock, fuel source, and energy storage material. Many reactions involving methanol are catalyzed by transition metal surfaces, on which hydrogen-bonded methanol overlayers form. As with water, the structure of these overlayers is expected to depend on a delicate balance of hydrogen bonding and adsorbate-substrate bonding. In contrast to water, however, relat...