The Lewis acidity of isolated framework metal sites in Beta zeolites was characterized with 15N isotopically labeled pyridine adsorption coupled with magic-angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy. The 15N chemical shift of adsorbed pyridine was found to scale with the acid character of both Lewis (Ti, Hf, Zr, Nb, Ta, and Sn) and Brønsted (B, Ga, and Al) acidic heteroato...

The use of biomasses that result from the agriculture and food industries in removing heavy metals from wastewaters is attracting increasing interest. We present a joined potentiometric and cross polarization magic angle spinning (CP-MAS) carbon-13 (13C) nuclear magnetic resonance (NMR) study on the interaction of olive stones with copper(II), nickel(II), and cadmium(II). The potentiometric mea...

Several solid state NMR techniques including magic-angle-spinning (MAS) and multiple-quantum (MQ) MAS experiments have been used to characterize various AlH3 samples. MAS-NMR spectra for the H and Al nuclei have been obtained on a variety of AlH3 samples that include the βand γ-phases as well as the most stable α-phase. While the dominant components in these NMR spectra correspond to the alumin...

new technique, at temperatures of 150°C or 450°C t provides planarization after a very deep etching step silicon is presented. Resist spinning and layer palerning as well as realization of bridges or cantilevers across deep holes becomes possible. The sacrificial wafer bonding technique contains a wafer bond step followed by an etch back. Results of (1) polymer bopding followed by dry etching a...

A two-step synthesis for multi-walled carbon nanotube (MWCNT) coating was reported that includes an electrochemical deposition followed by 10 eV hyperthermal proton bombardment at a dose as low as 1×1016 H+/cm2. Electrochemical deposition ensures an improved adhesion of MWCNT coating on metal substrates, while hyperthermal proton bombardment effectively induces inter-chain cross-linkages among ...

Multiwalled boron nitride nanotubes (BNNTs) have very attractive mechanical and thermal properties, e.g., elasticity, tensile strength, and high resistance to oxidation, and may be considered as ideal reinforcing agents in lightweight metal matrix composites. Herein, for the first time, Al-BNNT ribbons with various BNNT contents (up to 3 wt.%) were fabricated via melt spinning in an argon atmos...

During the last decade, incremental forming is an innovative processing method which has been strongly investigated. Its potential as a flexible manufacturing method was noticed. This paper aims to present a comparative study of the recent worldwide developments in the field of incremental sheet forming (ISF), as a flexible method for manufacturing hollow metal parts. There are pointed out its ...

Friction-spinning as an innovative incremental forming process enables large degrees of deformation in the field tube and sheet metal due to a self-induced heat generation zone. This paper presents new tool design with driven for targeted adjustment residual stress distributions friction-spinning process. Locally adapted depth are intended improve functionality workpieces, e.g. by delaying fail...