Heavy metal ions are harmful for entomopathogenic fungi. Derivatives of starch dialdehyde such as dihydrazone (DHZ), dithiosemicarbazone (DTSC), and dioxime (DOX) were used to form water-insoluble complexes with heavy metal ions. This phenomenon thus provided protection of entomopathogenic fungus Paecilomyces farinosus from the toxic effects of heavy metal ions. The fungus growth and the sporul...

interaction of floral pigments with metal ions can alter the final color of the petals. metal ions can affect stability of flowers final color by altering vacuolar ph and activity of enzymes involved in biosynthesis, destruction, accumulation and transition of pigments. in this study, contents of metal ions of petal tissue and their relationships with parameters of petal color analyzed and comp...

The hammerhead ribozyme is generally accepted as a well characterized metalloenzyme. However, the precise nature of the interactions of the RNA with metal ions remains to be fully defined. Examination of metal ion-catalyzed hammerhead reactions at limited concentrations of metal ions is useful for evaluation of the role of metal ions, as demonstrated in this study. At concentrations of Mn2+ ion...

We report on the acid dissociation constants (Ka) of diglycolamic acid-type ligands together with comprehensive data on the extraction performance of N,N-dioctyldiglycolamic acid (DODGAA) for 54 metal ions. The pKa of the diglycolamic acid framework was determined to be 3.54 ± 0.03 in water (0.1 M LiCl, 25°C) by potentiometric titration, indicating that DODGAA is strongly acidic compared with a...

BACKGROUND Metal-on-metal prostheses undergo wear and corrosion, releasing soluble ions and wear particles into the surrounding environment. Reports described early failures of the metal-on-metal prostheses, with histologic features similar to a Type IV immune response. Mechanisms by which metal wear products and metal ion causing this reaction are not completely understood, and the effects of ...

Metals are essential for the normal functioning of living organisms. Their uses in biological systems are varied, but are frequently associated with sites of critical protein function, such as zinc finger motifs and electron or oxygen carriers. These functions only require essential metals in minute amounts, hence they are termed trace metals. Other metals are, however, less beneficial, owing t...

This paper reviews some of the more interesting and recent phenomena associated with the metal ion cage chemistry involving hexaazamacropolycycles. Synthetic aspects are addressed in relation to making cages with smaller and larger hole sizes in order to modulate redox potentials and electron transfer rates. The introduction of substituents is also examined in relation to these factors along wi...

Abstract This chapter introduces a general protocol to transfer metal ions from aqueous solution to an organic medium, which involves mixing the aqueous solution of metal ions with an ethanolic solution of dodecylamine (DDA), and extracting the coordinating compounds formed between metal ions and DDA into toluene. This protocol could be applied toward transferring a wide variety of transition m...

Some of metal ions are the most dangerous pollutants due to their acute toxicity and carcionogenetiy. Exposure to high concentrations of these metal ions causes lung, nasal and throat cancers. Therefore, interest and demand is increasing for metal determination in biological and environmental samples [1]. Metal ions were generally determined with atomic absortion spectrophotometry or inductivel...

Larrea tridentata (creosote bush) is a plant that grows abundantly in the desert environment. This desert plant has been found naturally growing in heavy-metal contaminated soils. Previous experiments showed that the inactivated biomass of creosote bush was able to adsorb Cu(II) ions from aqueous solutions. The copper-binding capacity of the bush biomass that grows in heavy-metal uncontaminated...