the built up layer thickness in secondary deformation zone is one of the important parameters in metal cutting process. the built up layer (bul) is formed in second deformation zone near the tool-chip interface in the back of the chip. this parameter influences the tool life and machined surface quality. this bul should not be confused with the built up edge (bue). the deformation of the bul in...

The presence of toxic metals in drinking water has hazardous effects on human health. This study was conducted to develop GFP-based-metal-binding biosensors for on-site assay of toxic metal ions. GFP-tagged ArsR and CadC proteins bound to a cis element, and lost the capability of binding to it in their As- and Cd-binding conformational states, respectively. Water samples containing toxic metals...

The molecular chemistry of the f-elements, i.e. the lanthanides and actinides, is traditionally dominated by the use of carbon, nitrogen, oxygen or halide ligands. However, the use of metal-based fragments as ligands is underdeveloped, which contrasts to the field of d-block metal–metal complexes that have developed extensively over the last 50 years. Consequently, the use of metal-based fragme...

There are a wide range of physical defects which occur during metal forming processes. These defects, which may occur on the surface or be internal, are undesirable not only because of the surface appearance, but because they may adversely affect the strength, formability and other manufacturing characteristics of the material. Some physical defects in metal forming processes such as rolling an...

Introduction: Many of the petrologic characteristics of ureilites that are difficult to reconcile with normal igneous processes [1] can be explained by a smelting model, in which silicate mg (molar Mg/[Mg+Fe]) are controlled by carbon redox reactions [2-4]. However, their metal and siderophile element abundances appear to be inconsistent with such a model [5-7]. The smelting reaction (FeO + C →...

The common practice of remediating metal contaminated mine soils with compost can reduce metal mobility and promote revegetation, but the effect of introduced or colonising earthworms on metal solubility is largely unknown. We amended soils from an As/Cu (1150 mg As kg(-1) and 362 mg Cu kg(-1)) and Pb/Zn mine (4550 mg Pb kg(-1) and 908 mg Zn kg(-1)) with 0, 5, 10, 15 and 20% compost and then in...

The ability of DNA binding transcription factors to access cis-acting promoter elements is critical for transcriptional responses. We demonstrate that rapid transcriptional autoactivation by the Amt1 Cu metalloregulatory transcription factor from the opportunistic pathogenic yeast Candida glabrata is dependent on rapid metal-induced DNA binding to a single metal response element (MRE). In vivo ...

Metallothioneins are low-molecular-weight proteins capable of covalently binding heavy metal ions due to the presence of many cysteine residues in their sequences. We analyzed the predicted amino acid sequences of 19 metallothionein (7 from Arabidopsis thaliana and 12 from Oryza sativa) and their promoter sequences in silico in order to determine the potential regulatory cis-elements present in...

In the present study, effect of Ni alloying element on the characteristics of deposited weld metal of E7018-G electrode was evaluated. Therefore, electrodes contained different amounts of Ni (0-1.7wt.%) were designed, manufactured and welded via SMAW process. Microstructural studies revealed dichotomy effect of Ni on the deposited weld metal microstructure, i.e. increasing the Ni content up to ...

Metallic elements, ions and compounds produce varying degrees of toxicity in organisms with which they come into contact. Metal speciation is critical to understanding these adverse effects; the adjectives "heavy" and "toxic" are not helpful in describing the biological properties of individual elements, but detailed chemical structures are. As a broad generalization, the metallic form of an el...