To investigate the roles of different sulfur (S) species in controlling the partitioning and bioavailability of inorganic mercury (Hg) in anoxic sediments, we examined the differential binding of Hg with three key S species in anoxic sediment (mackinawite [FeS], pyrite [FeS2], and S(2-)) and then quantified their extraction by the gut juice of deposit-feeding sipunculans Sipunculus nudus. A seq...

Atsushi Kondo,† Hiroshi Noguchi,† Lucia Carlucci,‡ Davide M. Proserpio,‡ Gianfranco Ciani,‡ Hiroshi Kajiro,*,§ Tomonori Ohba,† Hirofumi Kanoh,*,† and Katsumi Kaneko† Graduate School of Science, Chiba UniVersity, Yayoi, Inage, Chiba 263-8522, Japan, Nippon Steel Corporation, Shintomi, Futtsu, Chiba 293-8511, Japan, and Dipartimento di Chimica Strutturale e Stereochimica Inorganica, UniVersità di...

IRMOF-3 nano/microcrystals with controllable morphologies and sizes were successfully obtained by a simple solvothermal method. The shape evolution of IRMOF-3 crystals from cube to truncated cube, cuboctahedron, truncated octahedron and finally to octahedron was achieved by adjusting the amount of surfactant. The surfaces of the IRMOF-3 nano/microstructures are affected by the reaction temperat...

The use of NMR spin-lattice relaxation experiments on water, or other proton-containing fluids, in a porous solid as a pore structure/size measurement tool has been recently reported for porous solids with pore size greater than ~ 5 nm. This approach has numerous advantages, as compared to nitrogen sorption/ condensation and mercury porosimetry, including no network/percolation effects, no pore...

the sorption behavior of loofa-immobilized phanerochaete chrysosporium mycelia in two forms, live (l) and heat-inactivated (hia), was studied for the removal of hg2+ ions from aqueous solution. using the langmuir isotherm, the two key parameters for the sorption performance, qm and the coefficient b, were obtained; the qm values for hg2+ ions were 72.46 mg/g and 92.59 mg/g and the b coefficient...

activated charcol phase loaded with 2-propylpiperidine-1-carbodithioate (ppcd) were synthesized based on chemical binding and physical adsorption approaches. the stability of a chemically modified ppcd especially in concentrated hydrochloric acid which was then used as a recycling and pre-concentration reagent for further uses of activated charcol immobilized ppcd. the application of this activ...