Crystal engineering concept has been utilized to modify the physico-chemical parameters of a naturally occurring alkaloid, quinine sulphate, by exploring its H-bond interactions to generate different forms. Quinine sulphate is found to exist in four different crystal forms. The Forms I and II depict endo/exo events suggesting conversion of metastable low melting forms to higher melting and stab...

Various melting-related phenomena (like surface melting, size dependence of melting temperature, melting of few nm-size particles, and overheating at very fast heating rate) are of great fundamental and applied interest, although the corresponding theory is still lacking. Here we develop an advanced phase-field theory of melting coupled to mechanics, which resolves numerous existing contradicti...

This paper deals with a novel interactive approach of Artificial Neural Network (ANN) as an optimization tool for optimizing process parameters of rotary furnace. This approach solves a very challenging problem in the area of rotary furnace i. e. selection of optimal process parameters for producing homogenous quality castings. Rotary furnace involves several critical parameters like flame temp...

We have assessed the microbial ecology on the surface of Mittivakkat glacier in SE-Greenland during the exceptional high melting season in July 2012 when the so far most extreme melting rate for the Greenland Ice Sheet has been recorded. By employing a complementary and multi-disciplinary field sampling and analytical approach, we quantified the dramatic changes in the different microbial surfa...

Sea-level rise from melting of polar ice sheets is one of the largest potential threats of future climate change. Polar warming by the year 2100 may reach levels similar to those of 130,000 to 127,000 years ago that were associated with sea levels several meters above modern levels; both the Greenland Ice Sheet and portions of the Antarctic Ice Sheet may be vulnerable. The record of past ice-sh...

For several years, progress has been made in understanding surface melting as well as surface roughening of various crystals such as ice, lead, rare gases etc. A so-called quasi-liquid layer (QLL), caused by surface melting, is expected to influence the vapor growth mechanism of crystals at temperatures not far below their melting points. The effect of the self-diffusion coefficient D of a QLL ...

Dynamic change at the marine-terminating margins of the Greenland Ice Sheet may be initiated by the ocean, particularly where subglacial runoff drives vigorous ice-marginal plumes and rapid submarine melting. Here we model submarine melt-driven undercutting of tidewater glacier termini, simulating a process which is key to understanding ice-ocean coupling. Where runoff emerges from broad subgla...

In this work, the thermal environment inside the furnace of a dynamic mechanical analyser was investigated by putting a standard sample in distinct positions inside the furnace. Penetration experiments were carried out in order to compare the measured melting temperature of the sample with the theoretical melting temperature. The thermal gradients were investigated for three distinct modes: com...

The selection of raw materials affects the rate of batch-to-glass conversion. In all-electric melters, foam under the batch blanket limits the heat flux from the molten glass, thus slowing the rate of melting. Our study, in which we compare the melting behaviors of three batches formulated to vitrify high-alumina high-level waste, shows that a slowly dissolving refractory component can cause ex...

Carbon tetrachloride is an extremely good extreme-pressure (EP) lubricant additive at low concentrations (< 3 wt% chlorine) since it can react to form a high-melting-point Fe3C antiseizure layer. In contrast, small hydrogen-containing additive molecules (CH2C12, CHC13) decompose to form FeC12 which melts at ,,~940 K and limits the maximum seizure load to N 3500 N as measured in a pin and v-bloc...