nanocomposites based on polyamide 6 (pa6) and poly(ethylene-co-1-butene)-graft-maleic anhydride (eb-g-mah) blends have been prepared via melt mixing. the effect of blend ratio and organoclay concentration onthe crystallization and melting behavior of specimens were studied. three types of commercial organo-modifiedclay (cloisite 30b, cloisite 15a and cloisite 20a) were employed to assess the im...

In this research, thermoplastic polyurethane (TPU) and clay nanoparticles were incorporated into poly (butylene terephthalate) (PBT) to improve the impact and tensile properties. The PBT/TPU (90/10, 80/20 and 70/30) samples were prepared by melt mixing using a co-rotating twin-screw extruder followed by injection molding. At the next stage, clay nanoparticles of different weight fractions were ...

The solid state polymerization (SSP) of PET/PC reactive extrusion blends with and without cobalt catalyst at different polymer ratios was studied. Thermal and rheological evaluations were performed. DSC results showed changes in the PET’s T g , T ch , T m and X c . The melt flow rate (MFR) decreased for PET and the blends. The intrinsic viscosity increased. The variation in calorimetric and rhe...

The Non-Linear Strain Energy Equivalence Theory, a semi-empirical model, is utilized to predict longterm creep from short-term compressive stress-strain experiments conducted at different strain rates. Stress-strain experiments in uni-axial compression are performed at strain rates of 3 and 0.03 %/minute to predict creep behavior and stress-strain data at several strain rates for an immiscible ...

In this work, biopolymer-based nanocomposites with antimicrobial properties were prepared via melt-compounding. In particular, graphene nanoplatelets (GnPs) as fillers and an antibiotic, i.e., ciprofloxacin (CFX), as biocide were incorporated in a commercial biodegradable polymer blend of poly(lactic acid) (PLA) and a copolyester (BioFlex®). The prepared materials were characterized by scanning...

Attempts were made to modify polypropylene fibers by melt blending with polyethylene terephthalate in order to enhance the dyeability of the resultant fiber. Five blends of polypropylene/polyethylene terephthalate/compatibilizer were prepared and subsequently spun into fibers. Three disperse dyes were used to dye such modified fibers at boiling and 130 °C. The dyeing performance of the blend fi...

We perform molecular dynamics simulations on a bead-spring model of pure polymer grafted nanoparticles (PGNs) and of a blend of PGNs with a polymer melt to investigate the correlation between PGN design parameters (such as particle core concentration, polymer grafting density, and polymer length) and properties, such as microstructure, particle mobility, and viscous response. Constant strain-ra...

Graphene nanoplatelets (xGnP) were investigated as a novel nano-reinforcement filler in poly(lactic acid)(PLA)/poly(ethylene glycol)(PEG) blends by the melt blending method. PLA was first plasticized by PEG in order to improve its flexibility and thereby overcome its problem of brittleness. Then, xGnP was incorporated into the PLA/PEG blend. The prepared nanocomposites exhibited a significant i...