Lead(II) bromide (PbBr2, 99.999% trace metals basis), lead(II) iodide (PbI2, 99.999% trace metals basis), cesium carbonate (Cs2CO3, reagentPlus, 99%), iodine (I2, 99.99%), hydrochloric acid (HCl, ACS reagent, ≥ 37%), hydriodic acid (HI, 57wt.% in H2O), hydrobromic acid (HBr, 48 wt. % in H2O, ≥99.99%), indium(III) acetate (In(Ac)3, 99.99%), copper(I) iodide (CuI, purum, ≥99.5%), 1-dodecanethiol ...

Applying the cw laser fluorescence method, the cross sections for the fine structure mixing and quenching of the Cs 6P state, induced by collisions with ground-state caesium atoms and molecules, have been measured. Caesium atoms were optically excited to the 5DJ states via quadrupole-allowed 6S1/2 → 5DJ transitions, while the resonance states were populated by the radiative and collisional 5DJ ...

Applying the cw laser absorption and fluorescence method the cross sections for the fine-structure mixing and quenching of the caesium 5DJ states have been measured in pure caesium vapour. Caesium atoms were optically excited to the 5D5/2 state via the quadrupole-allowed 6S1/2 → 5D5/2 transition. The ground-state caesium density N0, obtained from the absorption at the pumped quadrupole transiti...

A concise total synthesis of PDE-II featuring copper-mediated double aryl amination with the combination of CuI, CsOAc, and Cs2CO3 is described. The highly substituted pyrroloindole skeleton was constructed by a one-pot five-step sequence including double aryl amination, beta-elimination, deprotection of a Cbz group, and removal of an Ns group followed by rearomatization.

Efficient palladium-catalysed cascade cyclisation to form spiroindoles is developed. Treatment of indoles bearing a propargyl chloride side chain at the 3-position with various external nucleophiles in the presence of a catalytic amount of Pd2(dba)3·CHCl3/dppb and Cs2CO3 in THF gives fused tetracyclic spiroindoles in moderate to good yields.

1. The method of sedimentation equilibrium in a gradient of caesium chloride has been applied to the preparation of blood-group-specific glycoproteins from human ovarian-cyst fluids: it is shown that virtually complete separation from contaminating protein is easily accomplished in a single step. 2. The glycoproteins isolated in this way have been characterized by analytical density-gradient ex...

Pseudorotaxane complexes of squaraine dyes and tetralactam macrocycles are converted into permanently interlocked rotaxane structures using copper-catalyzed and copper-free cycloaddition reactions with bulky stopper groups. The photophysical properties of the encapsulated squaraine depend on the structure of the macrocycle. In one case, squaraine rotaxanes are produced in near-quantitative yiel...

A novel dipole force trap was developed for trapping caesium atoms in the lower hyperfine level of the ground state and in preliminary experiments a cloud of ≈1000 atoms was trapped. The viability of the trap is discussed, including suggestions for amendments to the trap design and problems that might occur which are intrinsic to the caesium atom.

The ability to observe chemical reactions at the molecular level convincingly demonstrates the physical and chemical phenomena occurring throughout a reaction mechanism. Videos obtained through in situ transmission electron microscopy (TEM) revealed the oxidation of catalytic soot under practical reaction conditions. Carbon oxidation reactions using Ag/SiO2 or Cs2CO3/nepheline catalysts were pe...