Frustration of crystallisation by locally favoured structures is critically important in linking the phenomena of supercooling, glass formation, and liquid-liquid transitions. Here we show that the putative liquid-liquid transition in n-butanol is in fact caused by geometric frustration associated with an isotropic to rippled lamellar liquid-crystal transition. Liquid-crystal phases are general...

Beamsteering using liquid crystals can be achieved with refractive or diffractive implementations. The common thread in these various structures is that the liquid crystal is employed as an optical phase modulator. Either nematic or smectic liquid crystal phases can be used to shift the phase of light and steer an optical beam. Various liquid crystal optical phase modulating schemes will be des...

Differential scanning calorimetry and X-ray diffraction of anhydrous and hydrated N-palmitoylgalactosylsphingosine (NPGS) show evidence of complex polymorphic behavior and interconversions between stable and metastable structural forms. Anhydrous NPGS exhibits three lamellar crystal forms (A, B, and B') at temperatures below 143 degrees C and a liquid-crystal form between 143 and 180 degrees C ...

Synthetic routes towards monodisperse polyhedral liquid-crystalline silsesquioxanes are described. The liquid-crystalline phase behaviour of these structurally uniform materials, with various silsesquioxane core and mesogenic side-chain structures, were analysed and compared with those of related oligomeric and polymeric materials. Common features of the solid-state behaviour of these organic/i...

In gaseous state, the particles are randomly distributed in free space. There is no correlation between the particles that move in independent trajectories bouncing off of each other. The gases can not be seen because average distance between particles is larger than the wave length of visible light. In liquids, the particles are also distributed randomly in space but with specific correlation ...

The optical switching times of liquid-crystal cells using 5CB, 5OCB and PCH5 liquid crystal materials have been characterized as a function of applied voltage, V, and temperature, T. The transition time from 90 to 10 % transmission scales as V and is limited to 50 to 30 ns by the breakdown electric field, ~ 10 V cm of the liquid crystal. The time from the initial voltage step to 90 % transmissi...

An optically triggered liquid crystal infiltrated Q-switched photonic crystal laser is demonstrated. A photonic crystal laser cavity was designed and fabricated to support two orthogonally polarized high-Q cavity modes after liquid crystal infiltration. By controlling the liquid crystal orientation via a layer of photoaddressable polymer and a writing laser, the photonic crystal lasing mode can...